Structure and magentic properties of novel chelate complexes of copper(II) and nickel(II) with nitroxide radical ethyl-2-(1-oxyl-2,2,5,5-tetramethylimidazolidin-4-yliden)-3-oxopropanoate

Structure and magentic properties of novel chelate complexes of copper(II) and nickel(II) with nitroxide radical ethyl-2-(1-oxyl-2,2,5,5-tetramethylimidazolidin-4-yliden)-3-oxopropanoate Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2010, Volume: 51, Number: 5, Pages: 916-922 Pages count : 7 DOI: 10.1007/s10947-010-0139-3

Tags

nitroxide radicals; complexes; structure; magnetic properties

Authors

Burdukov A.B. ² , Bekker K.S. ^1,3 , Stepanov G.A. ¹ , Bogatyrev A.L. ¹ , Pervukhina N.V. ² , Bogomyakov A.S. ⁴ , Reznikov V.A. ^1,3

Affiliations

1	(Данные Web of science) Novosibirsk State Univ, Novosibrisk, Russia
2	(Данные Web of science) Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Inst Organ Chem, Siberian Div, Novosibirsk, Russia
4	(Данные Web of science) Russian Acad Sci, Int Tomog Ctr, Siberian Div, Novosibirsk, Russia

Chelate complexes of copper(II) and nickel(II) with anions of nitroxide radical ethyl-2-(1-oxyl-2,2,5,5-tetramethylimidazolidin-4-yliden)-3-oxopropanoate (HL) are synthesized. The compounds have molecular structure and zero magnetic dimensionality. CuL(2) crystallizes as two polymorphs having mononuclear structure. Ni(2)L(4) forms dimeric molecules by virtue of the bridging function of the aldehyde oxygen atoms. Magnetic properties of Ni(2)L(4) are determined by antiferromagnetic exchange interactions between the Ni(II) ions (-48(1) K) propagated through the oxygen bridges.

Burdukov A.B. , Bekker K.S. , Stepanov G.A. , Bogatyrev A.L. , Pervukhina N.V. , Bogomyakov A.S. , Reznikov V.A.
Structure and magentic properties of novel chelate complexes of copper(II) and nickel(II) with nitroxide radical ethyl-2-(1-oxyl-2,2,5,5-tetramethylimidazolidin-4-yliden)-3-oxopropanoate
Journal of Structural Chemistry. 2010. V.51. N5. P.916-922. DOI: 10.1007/s10947-010-0139-3 WOS Scopus

Бурдуков А.Б. , Мельникова-Беккер К.С. , Степанов Г.А. , Богатырев А.Л. , Первухина Н.В. , Богомяков А.С. , Резников В.А.
Структура и магнитные свойства новых хелатных комплексов меди(ii) и никеля(ii) с нитроксильным радикалом этил-2-(1-оксил-2,2,5,5-тетраметилимидазолидин-4-илиден)- 3-оксопропаноатом
Журнал структурной химии (J STRUCT CHEM+). 2010. Т.51. №5. С.951-956. РИНЦ

Published print:	Oct 1, 2010
Published online:	Nov 19, 2010

Web of science	WOS:000284428100016
Scopus	2-s2.0-78649466039
OpenAlex	W2094148579