Synthesis of 4-(omega-hydroxyalkyl)-2,6-di-tert-butylphenols and the properties of related sulfides

Synthesis of 4-(omega-hydroxyalkyl)-2,6-di-tert-butylphenols and the properties of related sulfides Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2010, Volume: 80, Number: 10, Pages: 2001-2006 Pages count : DOI: 10.1134/S1070363210100208

Authors

Krysin A. P. ¹ , Pustovskikh I. I. ¹ , Koptyug V. A. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

Reaction of 2,6-di-tert-butylphenol with aliphatic linear and branched diols in an alkaline medium at a temperature of 180-220A degrees C leads to the formation of 4-(omega-hydroxyalkyl)-2,6-di-tert-butylphenols. The increase in the product yield and reducing the reaction temperature was reached at the catalysis of this reaction with zinc oxide. The structure of the diphenylalkane derivatives generated in side reaction was proved and the structural influence of the length of the aliphatic residue on the antioxidant effectiveness of the sulfides derived from the corresponding hydroxyalkylphenols was examined.

Krysin A.P. , Pustovskikh I.I. , Koptyug V.A.
Synthesis of 4-(omega-hydroxyalkyl)-2,6-di-tert-butylphenols and the properties of related sulfides
Russian Journal of General Chemistry. 2010. V.80. N10. P.2001-2006. DOI: 10.1134/S1070363210100208 WOS Scopus РИНЦ

Published print:	Oct 1, 2010
Published online:	Nov 26, 2010

Web of science	WOS:000284650700020
Scopus	2-s2.0-78649911486
Elibrary	16708839
OpenAlex	W2073476769