Oxidative addition of verdazyl halogenides to Pd(PPh3)(4)

Oxidative addition of verdazyl halogenides to Pd(PPh3)(4) Full article

Journal

New Journal of Chemistry
ISSN: 1144-0546

Output data

Year: 2019, Volume: 43, Number: 38, Pages: 15293-15301 Pages count : 9 DOI: 10.1039/c9nj03361k

Authors

Petunin Pavel, V ^1,2 , Votkina Darya E. ¹ , Trusova Marina E. ¹ , Rybalova Tatyana, V ^3,4 , Amosov Evgeny, V ³ , Uvarov Mikhail N. ^4,5 , Postnikov Pavel S. ^1,6 , Kazantsev Maxim S. ^3,4 , Mostovich Evgeny A. ⁴

Affiliations

1	(Данные Web of science) Tomsk Polytech Univ, 30 Lenin Ave, Tomsk 634050, Russia
2	(Данные Web of science) Siberian State Med Univ, 2 Moskovskiy Trakt, Tomsk 634050, Russia
3	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, 9 Lavrentiev Ave, Novosibirsk 630090, Russia
4	(Данные Web of science) Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
5	(Данные Web of science) Russian Acad Sci, Siberian Branch, VV Voevodsky Inst Chem Kinet & Combust, 3 Inst Skaya Str, Novosibirsk 630090, Russia
6	(Данные Web of science) Univ Chem & Technol, 5 Tech, Prague 16628, Czech Republic

Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(ii) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities.

Petunin P.V. , Votkina D.E. , Trusova M.E. , Rybalova T.V. , Amosov E.V. , Uvarov M.N. , Postnikov P.S. , Kazantsev M.S. , Mostovich E.A.
Oxidative addition of verdazyl halogenides to Pd(PPh3)(4)
New Journal of Chemistry. 2019. V.43. N38. P.15293-15301. DOI: 10.1039/c9nj03361k WOS Scopus РИНЦ

Web of science	WOS:000488843000026
Scopus	2-s2.0-85072819925
Elibrary	41679603
OpenAlex	W2971923287