Carbonylation of Polyfluorobenzocyclobutenones in a SbF5 Medium

Carbonylation of Polyfluorobenzocyclobutenones in a SbF5 Medium Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2019, Volume: 55, Number: 8, Pages: 1103-1111 Pages count : 9 DOI: 10.1134/S1070428019080086

Tags

carbonylation; polyfluorinated benzocyclobutenones; isochromenone; antimony pentafluoride

Authors

Zonov Ya, V ^1,2 , Karpov V.M. ¹ , Mezhenkova T., V ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Novosibirsk Inst Organ Chem, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia

The carbonylation of perfluoro-2-R-benzocyclobutenones (R = F, CF3, C2F5, C6F5) in a CO-SbF5 system is accompanied by transformations of the four-membered cycle in the substrate to form polyfluorinated 1H-isochromene derivatives. The reaction of perfluoro-2-R-benzocyclobutenes (R = F, CF3, C2F5) with (CF3CO)(2)O or CF3COOH in a SbF5 medium in a sealed ampule involves formation of polyfluorobenzocyclobutenones and their carbonylation under the reaction conditions.

Zonov Y.V. , Karpov V.M. , Mezhenkova T.,.V.
Carbonylation of Polyfluorobenzocyclobutenones in a SbF5 Medium
Russian Journal of Organic Chemistry. 2019. V.55. N8. P.1103-1111. DOI: 10.1134/S1070428019080086 WOS Scopus РИНЦ

Зонов Я.В. , Карпов В.М. , Меженкова Т.В.
Карбонилирование полифторбензоциклобутенонов в среде SBF5
Журнал органической химии (RUSS J ORG CHEM+). 2019. Т.55. №8. С.1193-1202. DOI: 10.1134/S0514749219080081 РИНЦ

Published print:	Aug 1, 2019
Published online:	Oct 7, 2019

Web of science	WOS:000489050100008
Scopus	2-s2.0-85073061517
Elibrary	41679517
OpenAlex	W2980266080