gamma-Hydroxypropylation of 2,6-Dialkyl(aryl)phenols with Allyl Alcohol and Its Derivatives

gamma-Hydroxypropylation of 2,6-Dialkyl(aryl)phenols with Allyl Alcohol and Its Derivatives Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2010, Volume: 80, Number: 11, Pages: 2290-2297 Pages count : 8 DOI: 10.1134/S1070363210110101

Authors

Krysin A.P. ¹ , Khalikova N.U. ¹ , Khlebnikova T.B. ² , Nogina N.I. ¹ , Mamatyuk V.I. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia

The composition of the products of the reaction of 2,6-disubstituted phenols with allyl alcohol and its derivatives in an alkaline medium was investigated, the conditions for carrying out the reaction with the predominant formation of 4-(3-hydroxypropyl)-2,6-dialkyl(aryl)phenols were found, and its mechanism was suggested. The reaction was examined on an industrial scale. An important result is the practical demonstration of alkaline catalysis performed under homogeneous conditions with participation of phenols, when the used alkaline catalyst is recovered in the process without the formation of waste waters.

Krysin A.P. , Khalikova N.U. , Khlebnikova T.B. , Nogina N.I. , Mamatyuk V.I.
gamma-Hydroxypropylation of 2,6-Dialkyl(aryl)phenols with Allyl Alcohol and Its Derivatives
Russian Journal of General Chemistry. 2010. V.80. N11. P.2290-2297. DOI: 10.1134/S1070363210110101 WOS Scopus РИНЦ

Published print:	Nov 1, 2010
Published online:	Dec 25, 2010

Web of science	WOS:000286663100010
Scopus	2-s2.0-79251474970
Elibrary	16713822
OpenAlex	W2033994958