Hydrogenation and conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol

Hydrogenation and conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2010, Volume: 46, Number: 12, Pages: 1786-1789 Pages count : 4 DOI: 10.1134/S1070428010120043

Authors

Ardashov O.V. ¹ , Genaev A.M. ¹ , Il'ina I.V. ¹ , Korchagina D.V. ¹ , Volcho K.P. ¹ , Salakhutdinov N.F. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Hydrogenation of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol was studied. Nickel chloride-sodium tetrahydridoborate system turned out to selectively reduce the double bond in the isopropenyl group. The results of conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol and its partly and completely hydrogenated derivatives were in a good agreement with the NMR data.

Ardashov O.V. , Genaev A.M. , Il'ina I.V. , Korchagina D.V. , Volcho K.P. , Salakhutdinov N.F.
Hydrogenation and conformational analysis of (1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol
Russian Journal of Organic Chemistry. 2010. V.46. N12. P.1786-1789. DOI: 10.1134/S1070428010120043 WOS Scopus РИНЦ

Published print:	Dec 1, 2010
Published online:	Feb 5, 2011

Web of science	WOS:000286985900004
Scopus	2-s2.0-79951493042
Elibrary	16699700
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