Synthesis of binuclear complexes of PdCl2 with chiral ethylenediamine dioxime (H2L1), piperazine dioxime (H2L2), and propylenediamine dioxime (H2L3), the derivatives of the natural monoterpenoid (R)-(+)-limonene. The crystal structures of [Pd-2((HL1)-L-2)Cl-4] and [Pd-2(H2L2)Cl-4]

Synthesis of binuclear complexes of PdCl2 with chiral ethylenediamine dioxime (H2L1), piperazine dioxime (H2L2), and propylenediamine dioxime (H2L3), the derivatives of the natural monoterpenoid (R)-(+)-limonene. The crystal structures of [Pd-2((HL1)-L-2)Cl-4] and [Pd-2(H2L2)Cl-4] Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2009, Volume: 35, Number: 2, Pages: 128-135 Pages count : 8 DOI: 10.1134/S1070328409020079

Authors

Savel'eva Z.A. ¹ , Tkachev A.V. ² , Glinskaya L.A. ¹ , Bizyaev S.N. ² , Klevtsova R.F. ¹ , Larionov S.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

The diamagnetic complexes [Pd-2(H2L1)Cl-4] (I), [Pd-2(H2L2)Cl-4] (II), and Pd-2(H2L3)Cl-4(III) with chiral ligands derived from the natural monoterpenoid (R)-(+)-limonene are obtained (H-2 L-1 is ethylenediamine dioxime, H2L2 is piperazine dioxime, and H2L3 is propylenediamine dioxime). According to X-ray diffraction data, the crystal structures of complexes I and II are composed of binuclear acentric molecules. The coordination polyhedra PdN2Cl2 are trapeziums (squares distorted in a tetrahedral manner) made up of two N atoms of the tetradentate bridging cyclic ligands H2L1 and H2L2 and two Cl atoms. The fragments PdCl2 are trans in the complexes. The C-13 and H-1 NMR spectra of complexes I and II in CDCl3 also suggest their binuclear structures.

Savel'eva Z.A. , Tkachev A.V. , Glinskaya L.A. , Bizyaev S.N. , Klevtsova R.F. , Larionov S.V.
Synthesis of binuclear complexes of PdCl2 with chiral ethylenediamine dioxime (H2L1), piperazine dioxime (H2L2), and propylenediamine dioxime (H2L3), the derivatives of the natural monoterpenoid (R)-(+)-limonene. The crystal structures of [Pd-2((HL1)-L-2)Cl-4] and [Pd-2(H2L2)Cl-4]
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. V.35. N2. P.128-135. DOI: 10.1134/S1070328409020079 WOS Scopus РИНЦ

Савельева З.А. , Ткачев А.В. , Глинская Л.А. , Бизяев С.Н. , Клевцова Р.Ф. , Ларионов С.В.
Cинтез двухъядерных комплексов PdCl2 с хиральными этилендиаминдиоксимом (H2L1), пиперазиндиоксимом (H2L2) и пропилендиаминдиоксимом (HL3) производными природного монотерпеноида (r)-(+)-лимонена. кристаллическая структура [Pd2(H2L1)Cl4] и [Pd2(H2L2)Cl4]
Координационная химия (RUSS J COORD CHEM+). 2009. Т.35. №2. С.130-137. РИНЦ

Published print:	Feb 1, 2009
Published online:	Mar 7, 2009

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