Synthesis and Properties of the Cu(II) Complexes with Chiral Bis{(E)-[(1S,4R)-Delta(7,8)-1-Amino-2-para-Menthalidene]aminohydroxy}methane (L - a Derivative of Natural Terpenoid (R)-(+)-Limonene). Crystal Structure of the [Cu(L)(mu-Cl)CuCl3]center dot iso-PrOH Solvate

Synthesis and Properties of the Cu(II) Complexes with Chiral Bis{(E)-[(1S,4R)-Delta(7,8)-1-Amino-2-para-Menthalidene]aminohydroxy}methane (L - a Derivative of Natural Terpenoid (R)-(+)-Limonene). Crystal Structure of the [Cu(L)(mu-Cl)CuCl3]center dot iso-PrOH Solvate Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2009, Volume: 35, Number: 3, Pages: 200-209 Pages count : 10 DOI: 10.1134/S1070328409030075

Authors

Kokina T.E. ¹ , Glinskaya L.A. ¹ , Klevtsova R.F. ¹ , Boguslavskii E.G. ¹ , Sheludyakova L.A. ¹ , Bisyaev S.N. ² , Tkachev A.V. ² , Larionov S.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

The Cu2LCl4 complex (I) with chiral bis{(E)-[(1S,4R)-Delta(7,8)-1-amino-2-para-menthalidene]aminohydroxy} methane (L - a derivative of natural monoterpenoid (R)-(+)-limonene) is synthesized. The crystal structure of the solvate of complex I [Cu(L)(mu-Cl)CuCl3] center dot iso-PrOH (II) is determined by X-ray diffraction analysis. Structure II is based on molecules of the [Cu(L)(mu-Cl)CuCl3] binuclear complexes in which L is the tetradentate cycle-forming ligand. One Cl atom manifests the bridging function. The CuN4Cl coordination unit is a square pyramid, and CuCl 4 is a distorted tetrahedron. The iso-PrOH molecules are localized in cavities between the layers of structure II. The mu(eff) value for complex I is 2.56 mu B and indicates the absence of an appreciable interaction between the Cu2+ ions in the Cu(II)-Cl-Cu(II) exchange cluster. The compound CuLCl2 center dot H2O (III) is synthesized. The mu(eff) value for compound III is 1.6 mu B. Complexes I and III are studied by EPR and IR spectroscopy.

Kokina T.E. , Glinskaya L.A. , Klevtsova R.F. , Boguslavskii E.G. , Sheludyakova L.A. , Bisyaev S.N. , Tkachev A.V. , Larionov S.V.
Synthesis and Properties of the Cu(II) Complexes with Chiral Bis{(E)-[(1S,4R)-Delta(7,8)-1-Amino-2-para-Menthalidene]aminohydroxy}methane (L - a Derivative of Natural Terpenoid (R)-(+)-Limonene). Crystal Structure of the [Cu(L)(mu-Cl)CuCl3]center dot iso-PrOH Solvate
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. V.35. N3. P.200-209. DOI: 10.1134/S1070328409030075 WOS Scopus РИНЦ

Кокина Т.Е. , Глинская Л.А. , Клевцова Р.Ф. , Богуславский Е.Г. , Шелудякова Л.А. , Бизяев С.Н. , Ткачев А.В. , Ларионов С.В.
Синтез и свойства комплексов Cu(II) с хиральным бис-{(e)-[(1S,4R)- 7,8-1-амино-2-пара-менталиден]аминогидрокси}метаном (l) производным природного терпеноида (R)-(+)-лимонена. кристаллическая структура сольвата [Cu(l)( -Cl)CuCl3] · изо-PrOH
Координационная химия (RUSS J COORD CHEM+). 2009. Т.35. №3. С.202-211. РИНЦ

Published print:	Mar 1, 2009
Published online:	Mar 29, 2009

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