Polymerization of ethylene with self-immobilizing bis(phenoxyimine) catalytic systems

Polymerization of ethylene with self-immobilizing bis(phenoxyimine) catalytic systems Full article

Journal

Polymer Science - Series B
ISSN: 1560-0904

Output data

Year: 2009, Volume: 51, Number: 7-8, Pages: 276-282 Pages count : 7 DOI: 10.1134/S1560090409070100

Authors

Ivanchev S.S. ¹ , Vasil'eva M.Yu. ¹ , Ivancheva N.I. ¹ , Badaev V.K. ¹ , Oleinik I.I. ² , Sviridova E.V. ¹ , Tolstikov G.A. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, St Petersburg Branch, St Petersburg 197198, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

The kinetic features of polymerization of ethylene with five methylaluminoxane-activated selfim-mobilizing bis(phenoxyimine) complexes of titanium chloride, namely, bis{2-[(4-allyloxyphenylimino)methyl]-6-tert-butylphenoxy}TiCl2, bis{2-[(4-allyloxyphenylimino)methyl]-4,6-di-tert-butylphenoxy}TiCl2, bis{2-[(4-allyloxyphenylimino)methyl]-6-cumylphenoxy}TiCl2, bis{2-[(4-allyloxyphenylimino)methyl]-4,6-dicumylphenoxy}TiCl2, and bis{2-[(4-allyloxyphenylimino)methyl]-6-1-(4-tert-butylphenyl)ethylphenoxy}TiCl2 have been studied. The activity of these complexes in the polymerization of ethylene in the temperature range 20-80A degrees C and an ethylene pressure of 0.3 MPa has been investigated both in the homogeneous and polymer matrix-bound states. The self-immobilizing catalytic systems possess high activity (up to 40000 kg(PE)/mol(cat) MPa h) and give rise to ultrahigh-molecular-weight PE (M = (2-7) x 10(6)) with an improved morphology of polymer particles.

Ivanchev S.S. , Vasil'eva M.Y. , Ivancheva N.I. , Badaev V.K. , Oleinik I.I. , Sviridova E.V. , Tolstikov G.A.
Polymerization of ethylene with self-immobilizing bis(phenoxyimine) catalytic systems
Polymer Science - Series B. 2009. V.51. N7-8. P.276-282. DOI: 10.1134/S1560090409070100 WOS Scopus РИНЦ

Published print:	Aug 1, 2009
Published online:	Sep 8, 2009

Web of science	WOS:000269974000010
Scopus	2-s2.0-70349311195
Elibrary	15304463
OpenAlex	W2001090217