Skeletal transformations of perfluoro-1-ethyl-1-phenylbenzocyclobutene in the reaction with antimony pentafluoride

Skeletal transformations of perfluoro-1-ethyl-1-phenylbenzocyclobutene in the reaction with antimony pentafluoride Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2009, Volume: 130, Number: 10, Pages: 951-958 Pages count : DOI: 10.1016/j.jfluchem.2009.07.013

Tags

Skeletal transformations; Perfluoro-1-ethyl-1-phenylbenzocyclobutene; Antimony pentafluoride; X-ray structure; NMR spectroscopy

Authors

Mezhenkova Tatyana V. ¹ , Karpov Victor M. ¹ , Platonov Vyacheslav E. ¹ , Gatilov Yuri V. ¹

Affiliations

1	(Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Interaction of perfluoro-1-ethyl-1-phenylbenzocyclobutene with SbFs at room temperature gives, after treatment of the reaction mixture with H2O, perfluoro-4-[1-(2-methylphenyl)propylidene]cyclohexa-2,5-dienone as a main product. The reaction at 90-95 degrees C leads, after treatment with H2O, to a mixture of perfluorinated 9-ethyl-9-methyl-1,2,3,4-tetrahydro-9H-fluorene, 9-ethyl-4a-methyl-4,4a-dihydrofluoren-1-one, 3-ethyl-3-phenylphthalide, 1-hydroxy-2-methyl-1-phenylindan, 3-methyl-2-phenylindenone and small amounts of other products. (C) 2009 Elsevier B.V. All rights reserved.

Mezhenkova T.V. , Karpov V.M. , Platonov V.E. , Gatilov Y.V.
Skeletal transformations of perfluoro-1-ethyl-1-phenylbenzocyclobutene in the reaction with antimony pentafluoride
Journal of Fluorine Chemistry. 2009. V.130. N10. P.951-958. DOI: 10.1016/j.jfluchem.2009.07.013 WOS Scopus РИНЦ

Published print:

Oct 1, 2009

Web of science	WOS:000271345400014
Scopus	2-s2.0-70249134527
Elibrary	15296766
OpenAlex	W1991122357