The first example of the ortho-directing effect of the weakly coordinating substituent [-BF3](-) in the catalytic hydrodefluorination of the pentafluorophenyltrifluoroborate anion

The first example of the ortho-directing effect of the weakly coordinating substituent [-BF3](-) in the catalytic hydrodefluorination of the pentafluorophenyltrifluoroborate anion Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2009, Volume: 19, Number: 5, Pages: 260-262 Pages count : DOI: 10.1016/j.mencom.2009.09.009

Authors

Adonin Nicolay Yu. ¹ , Prikhod'ko Sergey A. ¹ , Bardin Vadim V. ² , Parmon Valentin N. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, GK Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

The pentafluorophenyltrifluoroborate anion undergoes hydrodefluorination under the action of zinc in the presence of nickel complexes turning into the 2,3,4,5-tetrafluoroborate anion.

Adonin N.Y. , Prikhod'ko S.A. , Bardin V.V. , Parmon V.N.
The first example of the ortho-directing effect of the weakly coordinating substituent [-BF3](-) in the catalytic hydrodefluorination of the pentafluorophenyltrifluoroborate anion
Mendeleev Communications. 2009. V.19. N5. P.260-262. DOI: 10.1016/j.mencom.2009.09.009 WOS Scopus РИНЦ

Published print:

Sep 1, 2009

Web of science	WOS:000271368800009
Scopus	2-s2.0-70349313253
Elibrary	15307722
OpenAlex	W2058293916