Luminescence properties of complexes Ln(Phen)(C6F5COO)(3) (Ln = Tb, Eu) and Ln(C6F5COO)(3) center dot nH(2)O (Ln = Tb, n=2; Ln = Eu, n=1). Structures of the [Tb-2(H2O)(8)(C6F5COO)(6)] complex and its isomer in the supramolecular compound [Tb-2(H2O)(8)(C6F5COO)(6)] center dot 2C(6)F(5)COOH

Luminescence properties of complexes Ln(Phen)(C6F5COO)(3) (Ln = Tb, Eu) and Ln(C6F5COO)(3) center dot nH(2)O (Ln = Tb, n=2; Ln = Eu, n=1). Structures of the [Tb-2(H2O)(8)(C6F5COO)(6)] complex and its isomer in the supramolecular compound [Tb-2(H2O)(8)(C6F5COO)(6)] center dot 2C(6)F(5)COOH Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2009, Volume: 35, Number: 11, Pages: 798-806 Pages count : 9 DOI: 10.1134/S1070328409110025

Authors

Larionov S.V. ¹ , Glinskaya L.A. ¹ , Leonova T.G. ¹ , Klevtsova R.F. ¹ , Uskov E.M. ¹ , Platonov V.E. ² , Karpov V.M. ² , Fadeeva V.P. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

Complexes Ln(Phen)(C6F5COO)(3) (Ln = Tb, Eu; Phen = 1,10-phenanthroline) (I, II) are synthesized. At 300 K these complexes and compounds Ln(C6F5COO)(3) center dot nH(2)O (Ln = Tb, n = 2; Ln = Eu, n = 1) (III, VI) possess photoluminescence (bright in the case of I and II). In the spectrum of compound I the line at 545 nm (transition (5) D (4) -> (7) F (5)) is most intense, whereas in the spectrum of compound II the most intense is the line at 613 nm (transition (5) D (0) -> (7) F (2)). The replacement of Phen by water decreases the luminescence intensity. The compound [Tb-2(H2O)(8)(C6F5COO)(6)] center dot 2C(6)F(5)COOH (IV) is synthesized. According to the X-ray diffraction data, in structure IV the molecules of the binuclear Tb(III) complex with the C6F5COOH molecules form a supramolecular ensemble due to hydrogen bonding. The C6F5COO- ligands perform the monodentate and bidentate bridging function, resulting in the opening of the eight-membered cycle Tb2C2O4. The TbO8 polyhedron is a distored tetragonal antiprism. The crystals of the binuclear complex [Tb-2(H2O)(8)(C6F5COO)(6)] (V) are obtained in which the C6F5COO- ligands are monodentate and tridentate bridging cyclic, which results in the closure of two four-membered cycles TbO2C and one four-membered cycle Tb2O2. The TbO9 polyhedron is a distorted monocapped tetragonal antiprism.

Larionov S.V. , Glinskaya L.A. , Leonova T.G. , Klevtsova R.F. , Uskov E.M. , Platonov V.E. , Karpov V.M. , Fadeeva V.P.
Luminescence properties of complexes Ln(Phen)(C6F5COO)(3) (Ln = Tb, Eu) and Ln(C6F5COO)(3) center dot nH(2)O (Ln = Tb, n=2; Ln = Eu, n=1). Structures of the [Tb-2(H2O)(8)(C6F5COO)(6)] complex and its isomer in the supramolecular compound [Tb-2(H2O)(8)(C6F5COO)(6)] center dot 2C(6)F(5)COOH
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. V.35. N11. P.798-806. DOI: 10.1134/S1070328409110025 WOS Scopus РИНЦ

Ларионов С.В. , Глинская Л.А. , Леонова Т.Г. , Клевцова Р.Ф. , Усков Е.М. , Платонов В.Е. , Карпов В.М. , Фадеева В.П.
Люминесцентные свойства комплексов ln(phen)(c6f5coo)3 (ln = tb, eu) и ln(c6f5coo)3 · nh2o (ln = tb, n = 2; ln = eu, n = 1). структуры комплекса [tb2(h2o)8(c6f5coo)6] и его изомера в супрамолекулярном соединении [tb2(h2o)8(c6f5coo)6] · 2c6f5cooh
Координационная химия (RUSS J COORD CHEM+). 2009. Т.35. №11. С.808-816. РИНЦ

Published print:	Nov 1, 2009
Published online:	Nov 15, 2009

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