Fluorination of aromatic compounds with N-fluorobenzenesulfonimide under solvent-free conditions

Fluorination of aromatic compounds with N-fluorobenzenesulfonimide under solvent-free conditions Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2009, Volume: 45, Number: 10, Pages: 1468-1473 Pages count : 6 DOI: 10.1134/S107042800910008X

Authors

Andreev R.V. ¹ , Borodkin G.I. ¹ , Shubin V.G. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

Reactions of N-fluorobenzenesulfonimide with methylbenzenes, phenols, and phenol ethers were studied under solvent-free conditions. The rate constant ratio for the reactions with mesitylene and durene indicates polar mechanism of the process. Solvent-free fluorination of aromatic compounds with N-fluorobenzenesulfonimide in some cases is more selective than reactions with other N-F reagents in a solvent.

Andreev R.V. , Borodkin G.I. , Shubin V.G.
Fluorination of aromatic compounds with N-fluorobenzenesulfonimide under solvent-free conditions
Russian Journal of Organic Chemistry. 2009. V.45. N10. P.1468-1473. DOI: 10.1134/S107042800910008X WOS Scopus РИНЦ

Published print:	Oct 1, 2009
Published online:	Nov 15, 2009

Web of science	WOS:000271810500008
Scopus	2-s2.0-70450201384
Elibrary	15297147
OpenAlex	W2119880675