Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction

Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2008, Volume: 18, Number: 6, Pages: 318-319 Pages count : 2 DOI: 10.1016/j.mencom.2008.11.010

Authors

Trofimov Boris A. ¹ , Vasilevsky Sergei F. ² , Gusarova Nina K. ¹ , Malysheva Svetlana R. ¹ , Baranov Denis S. ² , Mamatyuk Victor I. ³ , Gatilov Yurii V. ³

Affiliations

1	(Данные Web of science) Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
2	(Данные Web of science) Russian Acad Sci, Inst Chem Kinet & Combust, Siberian Branch, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

The complex [(Z-PhCH=CH)(3)P](2)PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 degrees C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P](2)PdCl2, the most common catalyst for this type of reactions.

Trofimov B.A. , Vasilevsky S.F. , Gusarova N.K. , Malysheva S.R. , Baranov D.S. , Mamatyuk V.I. , Gatilov Y.V.
Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction
Mendeleev Communications. 2008. V.18. N6. P.318-319. DOI: 10.1016/j.mencom.2008.11.010 WOS Scopus РИНЦ

Published print:

Nov 1, 2008

Web of science	WOS:000261850900010
Scopus	2-s2.0-56249087243
Elibrary	13578123
OpenAlex	W2017143985