A brave new world: the heteroatom chemistry of 1,3,2,4-benzodithiadiazines and related compounds

A brave new world: the heteroatom chemistry of 1,3,2,4-benzodithiadiazines and related compounds Full article

Journal

European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682

Output data

Year: 2008, Number: 5, Pages: 655-672 Pages count : 18 DOI: 10.1002/ejic.200701051

Tags

antiaromaticity; fluorine heteroatom chemistry; sulfur-nitrogen heterocycles; molecular structures; persistent radicals; reactivity synthesis

Authors

Blockhuys Frank ¹ , Gritsan Nina P. ^2,3 , Makarov Alexander Yu. ⁴ , Tersago Karla ¹ , Zibarev Andrey V. ^2,4

Affiliations

1	(Данные Web of science) Univ Antwerp, Dept Chem, Univ Pl 1, B-2610 Antwerp, Belgium
2	(Данные Web of science) Novosibirsk State Univ, Dept Phys, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Inst Chem Kinet & Combust, Novosibirsk 630090, Russia
4	(Данные Web of science) Russian Acad Sci, Inst Organ Chem, Novosibirsk 630090, Russia

This review highlights the most important advances in the heteroatom chemistry of 1,3,2,4-benzodithiadiazines (pi-excessive and formally antiaromatic heterocycles), covering methods for synthesis, nontrivial features of the molecular and pi-electronic structure, spectral properties, and reactivity, in particular the transformations into persistent pi-radicals. The chemistry of 1,3,2,4-benzodithiadiazines is compared to that of related chalcogen-nitrogen compounds, both cyclic and acyclic. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

Blockhuys F. , Gritsan N.P. , Makarov A.Y. , Tersago K. , Zibarev A.V.
A brave new world: the heteroatom chemistry of 1,3,2,4-benzodithiadiazines and related compounds
European Journal of Inorganic Chemistry. 2008. N5. P.655-672. DOI: 10.1002/ejic.200701051 WOS Scopus РИНЦ

Published online:	Jan 30, 2008
Published print:	Feb 1, 2008

Web of science	WOS:000254593800001
Scopus	2-s2.0-53449084267
Elibrary	13579721
OpenAlex	W1964558135