Abstract: The reaction of perfluorinated benzocyclobutene and tetraline with SiO(2)-SbF(5) led to the formation in a high yield of their mono- and further dicarbonyl derivatives. The monocarbonyl derivatives on heating with SbF(5) underwent disproportionation into the corresponding perfluorobenzocycloalkenes and diketones. Both mono- and diketones in the SbF5 medium are liable to suffer Skeleton rearrangements yielding five- and six-membered oxygen-containing heterocycles and/or products of the opening of the alicyclic fragment of the substrate, and from the perfluorobenzocyclobutenone compounds were also obtained with a number of carbon atoms greater than that of the initial ketone.

Cite: Zonov Y.V. , Karpov V.M. , Platonov V.E. , Gatilov Y.V.
Reaction of perfluorobenzocycloalkenes with SiO(2)-SbF(5) and skeleton transformations of their carbonyl derivatives in SbF(5) medium
Russian Journal of Organic Chemistry. 2008. V.44. N2. P.202-217. DOI: 10.1134/S107042800802005X WOS Scopus РИНЦ

ArticleLinkType.TRANSLATED_TO_ORIGINAL: Зонов Я.В. , Карпов В.М. , Платонов В.Е. , Гатилов Ю.В.
Взаимодействие перфторбензоциклоалкенов с sic2-sbf5 и скелетные превращения их карбонильных производных в среде sbf5
Журнал органической химии (RUSS J ORG CHEM+). 2008. Т.44. №2. С.212-226. РИНЦ

Dates:

Published print:	Feb 1, 2008
Published online:	Jan 19, 2011

Identifiers:

Web of science	WOS:000254140900005
Scopus	2-s2.0-43249099343
Elibrary	13566388
OpenAlex	W2111512249

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