Syntheses of chiral fused 4,5-diazafluorene-bis(nopinane) derivatives

Syntheses of chiral fused 4,5-diazafluorene-bis(nopinane) derivatives Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2019, Volume: 29, Number: 5, Pages: 584-586 Pages count : 3 DOI: 10.1016/j.mencom.2019.09.036

Authors

Vasilyev Eugene S. ¹ , Bizyaev Sergey N. ¹ , Komarov Vladislav Yu. ^2,3 , Tkachev Alexey V. ^1,3

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia

Reaction of fused 4,5-diazafluorene bis(nopinane) with tere-phthalaldehyde, benzophenone, ninhydrin or anthraquinone in THE in the presence of TiCl4 and pyridine results in a formation of new chiral condensation products, which exhibit solvatochromism and pleochroism. Crystal structure of the key products has been determined by X-ray crystallography, and unusual colour behavior has been explained by DFT calculations.

Vasilyev E.S. , Bizyaev S.N. , Komarov V.Y. , Tkachev A.V.
Syntheses of chiral fused 4,5-diazafluorene-bis(nopinane) derivatives
Mendeleev Communications. 2019. V.29. N5. P.584-586. DOI: 10.1016/j.mencom.2019.09.036 WOS Scopus РИНЦ

Published print:

Sep 1, 2019

Web of science	WOS:000496341100036
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Elibrary	41713516
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