Expansion of the pentafluorobenzene ring of perfluoro-1, 2-diethyl-1-phenylbenzocyclobutene under the action of SbF5

Expansion of the pentafluorobenzene ring of perfluoro-1, 2-diethyl-1-phenylbenzocyclobutene under the action of SbF5 Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2008, Volume: 129, Number: 1, Pages: 64-67 Pages count : DOI: 10.1016/j.jfluchem.2007.09.005

Tags

fluorinated; benzocyclobutene; ring expansion; antimony pentafluoride

Authors

Mezhenkova Tatyana V. , Sinyakov Vladimir R. , Karpov Victor M. , Platonov Vyacheslav E. , Rybalova Tatjana V. , Gatilov Yuri V.

Affiliations

1	(Данные Web of science) NN vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Perfluoro-1,2-diethyl-1-phenylbenzocyclobutene under the action of SbF5 gives, after treatment of the reaction mixture with water, perfluoro-4-[1-(6-propyl-phenyl)-propylidene]cyclohexa-2,5-dienone along with the products of unusual pentafluorobenzene ring expansion - perfluorinated 4b,10-diethylbenzo[a]azulen-7(4bH)-one and 10-ethylbenzo[a]azulen-6(10H)-one. (C) 2007 Elsevier B.V. All rights reserved.

Mezhenkova T.V. , Sinyakov V.R. , Karpov V.M. , Platonov V.E. , Rybalova T.V. , Gatilov Y.V.
Expansion of the pentafluorobenzene ring of perfluoro-1, 2-diethyl-1-phenylbenzocyclobutene under the action of SbF5
Journal of Fluorine Chemistry. 2008. V.129. N1. P.64-67. DOI: 10.1016/j.jfluchem.2007.09.005 WOS Scopus РИНЦ

Published print:

Jan 1, 2008

Web of science	WOS:000252600700010
Scopus	2-s2.0-37249045654
Elibrary	13582256
OpenAlex	W2949960851