Electrochemical, ESR and quantum chemical study of 1-substituted naphthalenes and their radical anions

Electrochemical, ESR and quantum chemical study of 1-substituted naphthalenes and their radical anions Full article

Journal

Journal of Physical Organic Chemistry
ISSN: 0894-3230

Output data

Year: 2008, Volume: 21, Number: 1, Pages: 73-78 Pages count : DOI: 10.1002/poc.1288

Tags

electrochemical reduction; electrochemical oxidation; radical anions; radical cations; ESR spectroscopy; cyclic voltammetry; naphthalene derivatives

Authors

Vasilieva N. V. , Irtegova I. G. , Vaganova T. A. , Shteingarts V. D.

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Inst Organ Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

Electrochemical reduction and oxidation of a series of I-substituted naphthalenes (1-X-naphthalenes) have been studied by the method of cyclic voltammetry (CV). The first reduction peak of the majority of these compounds corresponds to a one-electron transfer to form the relatively stable radical anion (RA). For these species, ESR spectra have been registered and interpreted, the life time has been estimated. The first oxidation peaks of 1-X-naphthalenes are irreversible and correspond to a transfer of two or more electrons. Copyright (C) 2007 John Wiley & Sons, Ltd.

Vasilieva N.V. , Irtegova I.G. , Vaganova T.A. , Shteingarts V.D.
Electrochemical, ESR and quantum chemical study of 1-substituted naphthalenes and their radical anions
Journal of Physical Organic Chemistry. 2008. V.21. N1. P.73-78. DOI: 10.1002/poc.1288 WOS Scopus РИНЦ

Published print:

Jan 1, 2008

Web of science	WOS:000253286600011
Scopus	2-s2.0-39349092362
Elibrary	13569311
OpenAlex	W1980240670