Pendular rearrangement of epimeric 3b,4,4a,5-tetramethyl-3b,4,4a,5-tetrahydro-4H-cyclopropa[a]phenalen-5-yl cations

Pendular rearrangement of epimeric 3b,4,4a,5-tetramethyl-3b,4,4a,5-tetrahydro-4H-cyclopropa[a]phenalen-5-yl cations Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2007, Volume: 43, Number: 11, Pages: 1656-1660 Pages count : 5 DOI: 10.1134/S1070428007110127

Authors

Bushmelev V.A. ¹ , Genaev A.M. ¹ , Sal'nikov G.E. ¹ , Shubin V.G. ¹

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9

The kinetics of degenerate pendular rearrangement of 3b,exo-4,4a,5-tetramethyl-3b,4,4a,5-tetrahydro-4H-cyclopropa[a]phenalen-5-yl cation and its endo epimer, generated under conditions ensuring their long life, were studied by dynamic NMR spectroscopy. The rearrangement mechanism is discussed with account taken of the results of quantum-chemical calculations and published data for related rearrangements.

Bushmelev V.A. , Genaev A.M. , Sal'nikov G.E. , Shubin V.G.
Pendular rearrangement of epimeric 3b,4,4a,5-tetramethyl-3b,4,4a,5-tetrahydro-4H-cyclopropa[a]phenalen-5-yl cations
Russian Journal of Organic Chemistry. 2007. V.43. N11. P.1656-1660. DOI: 10.1134/S1070428007110127 WOS Scopus РИНЦ

Бушмелев В.А. , Генаев А.М. , Сальников Г.Е. , Шубин В.Г.
"маятниковая" перегруппировка эпимерных 3b,4,4а,5-тетраметил-3b,4,4а,5- тетрагидро-4h-циклопропа[a]фенален-5-ильных катионов
Журнал органической химии (RUSS J ORG CHEM+). 2007. Т.43. №11. С.1659-1663. РИНЦ

Published print:

Nov 1, 2007

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