Reaction of perfluorinated 1-ethyl-, 1,1-diethyl-, and 1,2-diethylcyclobutabenzenes with pentafluorobenzene in SbF5

Reaction of perfluorinated 1-ethyl-, 1,1-diethyl-, and 1,2-diethylcyclobutabenzenes with pentafluorobenzene in SbF5 Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2007, Volume: 43, Number: 11, Pages: 1677-1685 Pages count : 9 DOI: 10.1134/S1070428007110152

Authors

Sinyakov V.R. ¹ , Mezhenkova T.V. ¹ , Karpov V.M. ¹ , Platonov V.E. ¹

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9

Perfluoro(1-ethyl-1,2-dihydrocyclobutabenzene) reacts with pentafluorobenzene in SbF5 to give perfluoro(1-ethyl-2-phenyl-1,2-dihydrocyclobutabenzene). Analogous reaction of a mixture of perfluoro(1,1-diethyl-1,2-dihydrocyclobutabenzene) and perfluoro(1,2-diethyl-1,2-dihydrocyclobutabenzene) leads to the formation (after hydrolysis of the reaction mixture) of perfluorinated 7-phenyl-8,8-diethylbicyclo[4.2.0]octa-1,4,6-trien-3-one, 1,1-diethyl-2-(4-oxocyclohexa-2,5-dienylidene)-1,2-dihydrocyclobutabenzene, and 2-(pent-2-en-3-yl)benzophenone (from the 1,1-isomer) and perfluorinated (E)-1,2-diethyl-1-phenyl-1,2-dihydrocyclobutabenzene, 7,8-diethyl-8-phenylbicyclo[4.2.0]octa-1,4,6-trien-3-one, and 1-[2-(1-phenylprop-1-en-1-yl)-phenyl]propan-1-one (from the 1,2-isomer).

Sinyakov V.R. , Mezhenkova T.V. , Karpov V.M. , Platonov V.E.
Reaction of perfluorinated 1-ethyl-, 1,1-diethyl-, and 1,2-diethylcyclobutabenzenes with pentafluorobenzene in SbF5
Russian Journal of Organic Chemistry. 2007. V.43. N11. P.1677-1685. DOI: 10.1134/S1070428007110152 WOS Scopus РИНЦ

Синяков В.Р. , Меженкова Т.В. , Карпов В.М. , Платонов В.Е.
Взаимодействие перфторированных 1-этил-, 1,1- и 1,2-диэтилбензоцикло-бутенов с пентафтороензолом в среде sbf5
Журнал органической химии (RUSS J ORG CHEM+). 2007. Т.43. №11. С.1678-1686. РИНЦ

Published print:

Nov 1, 2007

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