Triosmium cluster with the bridging aminooxime derivative of pinane: Synthesis, crystal structure and conformational analysis

Triosmium cluster with the bridging aminooxime derivative of pinane: Synthesis, crystal structure and conformational analysis Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2007, Volume: 33, Number: 8, Pages: 594-600 Pages count : 7 DOI: 10.1134/S1070328407080088

Authors

Korenev V.S. ^1,2 , Kirin V.P. ¹ , Maksakov V.A. ¹ , Virovets A.V. ² , Tkachev S.V. ¹ , Potemkin V.A. ³ , Agafontsev A.M. ⁴ , Tkachev A.V. ⁴

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia
3	(Данные Web of science) Chelyabinsk State Univ, Chelyabinsk, Russia
4	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

The reaction of 1R,2R,5R-2-dimethylamino-2,6,6-trimethylbicyclo[3.1.1]heptane-3-one oxime (pinaneoxime) with OS3(CO)(1)0(()NCMe)(2) was used to synthesize the (P-H)OS3(mu-kappa(1)-O-N=C12H21N)(CO)(10) cluster with coordination of the ligand through the oxime O atom and invariable terpenoid structure. The structure of the synthesized cluster was determined by X-ray diffraction analysis. The theoretical conformational analysis of the above cluster in a solution and in crystal state was performed by a combined MM3/MERA method. The rotation of a ligand about the O(1)-N(2) bond was found impossible due to a high energy barrier (E > 550 kJ/mol).

Korenev V.S. , Kirin V.P. , Maksakov V.A. , Virovets A.V. , Tkachev S.V. , Potemkin V.A. , Agafontsev A.M. , Tkachev A.V.
Triosmium cluster with the bridging aminooxime derivative of pinane: Synthesis, crystal structure and conformational analysis
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2007. V.33. N8. P.594-600. DOI: 10.1134/S1070328407080088 WOS Scopus РИНЦ

Коренев В.С. , Кирин В.П. , Максаков В.А. , Вировец А.В. , Ткачев С.В. , Потемкин В.А. , Агафонцев А.М. , Ткачев А.В.
Синтез, кристаллическая структура и конформационный анализ трехосмиевого кластера с мостиковым аминооксимным производным пинана
Координационная химия (RUSS J COORD CHEM+). 2007. Т.33. №8. С.605-611. РИНЦ

Published print:

Aug 1, 2007

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