Cu(II) complexes with 4,6-Bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine, 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine: Synthesis and catalytic activity in ethylene polymerization reaction

Cu(II) complexes with 4,6-Bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine, 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine: Synthesis and catalytic activity in ethylene polymerization reaction Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2007, Volume: 33, Number: 8, Pages: 601-606 Pages count : 6 DOI: 10.1134/S107032840708009X

Authors

Bushuev M.B. ¹ , Krivopalov V.P. ² , Semikolenova N.V. ³ , Shvedenkov Yu.G. ¹ , Sheludyakova L.A. ¹ , Moskalenko G.G. ² , Lavrenova L.G. ¹ , Zakharov V.A. ³ , Larionov S.V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Div, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

The Cu(II) complexes with 4,6-bis(3,5-dimethyl-]H-pyrazole-1-yl)pyrimidine (0) and 4-(3,5-di dimethyl-1H-pyrazole-1-y1)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine (L-2) of the composition (CuLBr4)-Br-1 and Cu-2,L(2)A(4) (A = Cl, Br), respectively, were synthesized and studied by IR and magnetochemical methods. The molecular structure of the complexes is likely to be binuclear. In the presence of cocatalysts methylaluminoxane and triisobutylaluminium, the title complexes exhibit catalytic activity in the ethylene polymerization reaction.

Bushuev M.B. , Krivopalov V.P. , Semikolenova N.V. , Shvedenkov Y.G. , Sheludyakova L.A. , Moskalenko G.G. , Lavrenova L.G. , Zakharov V.A. , Larionov S.V.
Cu(II) complexes with 4,6-Bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine, 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine: Synthesis and catalytic activity in ethylene polymerization reaction
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2007. V.33. N8. P.601-606. DOI: 10.1134/S107032840708009X WOS Scopus РИНЦ

Бушуев М.Б. , Кривопалов В.П. , Семиколенова Н.В. , Шведенков Ю.Г. , Шелудякова Л.А. , Москаленко Г.Г. , Лавренова Л.Г. , Захаров В.А. , Ларионов С.В.
Синтез координационных соединений меди(ii) c 4,6-бис(3,5-диметил-1н-пиразол-1-ил)пиримидином, 4-(3,5-диметил-1H-пиразол-1-ил)-6-(3,5-дифенил-1H-пиразол-1-ил)пиримидином и их каталитическая активность в реакции полимеризации этилена
Координационная химия (RUSS J COORD CHEM+). 2007. Т.33. №8. С.612-617. РИНЦ

Published print:

Aug 1, 2007

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