A well feasible and general route to (organoethynyl)difluoroboranes, RHC equivalent to CBF2, and their perfluorinated analogues, RFC equivalent to CBF2

A well feasible and general route to (organoethynyl)difluoroboranes, RHC equivalent to CBF2, and their perfluorinated analogues, RFC equivalent to CBF2 Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2007, Volume: 128, Number: 7, Pages: 699-702 Pages count : 4 DOI: 10.1016/j.jfluchem.2006.12.012

Tags

fluoroboranes; fluoroborates; alk-1-ynylboron compounds; NMR spectroscopy

Authors

Bardin Vadim V. ¹ , Adonin Nicolay Yu. ¹ , Frohn Hermann-Josef ²

Affiliations

1	(Данные Web of science) Univ Duisburg Essen, Dept Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, SB, Novosibirsk 630090, Russia

A representative series of (organoethynyl)difluoroboranes RC equivalent to CBF2 (R=C4H9, (CH3)(3)C, CF3, C3F7, (CF3)(2)CF, CF3CF=CF, C4F9CF=CF, C6F5) was prepared by abstraction of fluoride from the corresponding K[RC equivalent to CBF3] salts with BF3 in appropriate solvents' (1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluorobutane, or dichloromethane). (c) 2007 Elsevier B.V. All rights reserved.

Bardin V.V. , Adonin N.Y. , Frohn H-J.
A well feasible and general route to (organoethynyl)difluoroboranes, RHC equivalent to CBF2, and their perfluorinated analogues, RFC equivalent to CBF2
Journal of Fluorine Chemistry. 2007. V.128. N7. P.699-702. DOI: 10.1016/j.jfluchem.2006.12.012 WOS Scopus РИНЦ

Published print:

Jul 1, 2007

Web of science	WOS:000248429900003
Scopus	2-s2.0-34250778255
Elibrary	13535217
OpenAlex	W2061270305