The high-temperature alicyclic ring contraction of 1,1-dichloroperfluorotetralin and the alicyclic ring opening of 1,1-dichloroperfluorobenzocyclobutene

The high-temperature alicyclic ring contraction of 1,1-dichloroperfluorotetralin and the alicyclic ring opening of 1,1-dichloroperfluorobenzocyclobutene Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2007, Volume: 128, Number: 7, Pages: 714-717 Pages count : DOI: 10.1016/j.jfluchem.2007.02.015

Tags

fluorinated; tetralin; benzocyclobutene; pyrolysis; ring contraction; ring opening

Authors

Karpov Victor M. , Mezhenkova Tatyana V. , Platonov Vyacheslav E.

Affiliations

1	(Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The pyrolysis of 1,1-dichloroperfluorotetralin (4) in a stream of argon gives a mixture contained perfluoro-1-methyleneindan (1), perfluoro-3-methylindene (6), 1,1-dichloroperfluoroindan (2) and perfluoroindene (7), while copyrolysis of tetralin 4 with CHClF2 gives a mixture of compounds 1, 6 in the absence of compounds 2 and 7. 1-Chloro-2-(1-chloro-2,2-difluorovinyl)-3,4,5,6-tetrafluorobenzene (12) is formed in the pyrolysis of 1,1-dichloroperfluorobenzocyclobutene (5) in a stream of argon as well as in a stream of CHClF2. (c) 2007 Elsevier B.V. All rights reserved.

Karpov V.M. , Mezhenkova T.V. , Platonov V.E.
The high-temperature alicyclic ring contraction of 1,1-dichloroperfluorotetralin and the alicyclic ring opening of 1,1-dichloroperfluorobenzocyclobutene
Journal of Fluorine Chemistry. 2007. V.128. N7. P.714-717. DOI: 10.1016/j.jfluchem.2007.02.015 WOS Scopus РИНЦ

Published print:

Jul 1, 2007

Web of science	WOS:000248429900006
Scopus	2-s2.0-34250774399
Elibrary	13539751
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