Nickel(II) and copper(II) complexes with chiral bis-alpha-thiooxime, the derivative of natural terpenoid (+)-3-carene: Synthesis and structures

Nickel(II) and copper(II) complexes with chiral bis-alpha-thiooxime, the derivative of natural terpenoid (+)-3-carene: Synthesis and structures Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2007, Volume: 33, Number: 7, Pages: 514-522 Pages count : 9 DOI: 10.1134/S107032840707007X

Authors

Larionov S.V. ¹ , Kokina T.E. ¹ , Agafontsev A.M. ² , Gorshkov N.B. ³ , Tkachev A.V. ² , Klevtsova R.F. ¹ , Glinskaya L.A. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia
3	(Данные Web of science) Novosibirsk State Univ, Novosibirsk 630090, Russia

Chiral bis-alpha-thiooxime (H2L1), the derivative of the natural monoterpenoid (+)-3-carene, was synthesized and used to prepare paramagnetic complexes of the composition M(H2L1)Cl-2 (M=Ni, Cu). The crystal structures of [Ni(H2L1)Cl-2] (I) and [Cu(H2L1)Cl-2] (II) were determined by X-ray diffraction analysis. Crystals I and II consist of mononuclear acentric molecules. The Ni2+ ion in a molecule of complex I coordinates two N atoms and two S atoms of a tetradentate chelating ligand (the H2L1 molecule) and two Cl atoms. The NiCl2N2S2 coordination core forms octahedron compressed along the apical N atoms. In a molecule of complex II, the Cu2+ ion coordinates two S atoms and the N atom of a tridentate chelating H2L1 ligand and two Cl atoms. The CuCl2NS2 coordination core forms a trigonal bipyramid.

Larionov S.V. , Kokina T.E. , Agafontsev A.M. , Gorshkov N.B. , Tkachev A.V. , Klevtsova R.F. , Glinskaya L.A.
Nickel(II) and copper(II) complexes with chiral bis-alpha-thiooxime, the derivative of natural terpenoid (+)-3-carene: Synthesis and structures
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2007. V.33. N7. P.514-522. DOI: 10.1134/S107032840707007X WOS Scopus РИНЦ

Ларионов С.В. , Кокина Т.Е. , Агафонцев А.М. , Горшков Н.Б. , Ткачев А.В. , Клевцова Р.Ф. , Глинская Л.А.
Синтез и строение координационных соединений Ni(II) и Cu(II) с хиральным бис- -тиооксимом производным природного терпеноида (+)-3-карена
Координационная химия (RUSS J COORD CHEM+). 2007. Т.33. №7. С.525-533. РИНЦ

Published print:

Jul 1, 2007

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