Reaction of 3-trimethylsilylprop-2-ynal with alpha-hydroxyamino oximes

Reaction of 3-trimethylsilylprop-2-ynal with alpha-hydroxyamino oximes Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2007, Volume: 43, Number: 4, Pages: 507-510 Pages count : 4 DOI: 10.1134/S1070428007040033

Authors

Demina M.M. ¹ , Novopashin P.S. ¹ , Sarapulova G.I. ¹ , Afonin A.V. ¹ , Tikhonov A.Ya. ² , Medvedeva A.S. ¹

Affiliations

1	Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia
2	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090, Russia

3-Trimethylsilylprop-2-ynal reacted with aliphatic alpha-hydroxyamino oximes in a chemoselective fashion at the aldehyde group to give hitherto unknown open-chain 3-trimethylsilylprop-2-yn-1-ylideneamine oxides. The possibility for intramolecular hydrogen bonding with participation of OH, C C, and N -> O groups in the products was studied by IR spectroscopy.

Demina M.M. , Novopashin P.S. , Sarapulova G.I. , Afonin A.V. , Tikhonov A.Y. , Medvedeva A.S.
Reaction of 3-trimethylsilylprop-2-ynal with alpha-hydroxyamino oximes
Russian Journal of Organic Chemistry. 2007. V.43. N4. P.507-510. DOI: 10.1134/S1070428007040033 WOS Scopus РИНЦ

Демина М.М. , Новопашин П.С. , Сарапулова Г.И. , Афонин А.В. , Тихонов А.Я. , Медведева А.С.
Взаимодействие з-триметилсилил-2-пропин-1-аля с 1,2-гидроксиламино-оксимами
Журнал органической химии (RUSS J ORG CHEM+). 2007. Т.43. №4. С.510-513. РИНЦ

Published print:

Apr 1, 2007

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