Synthesis of epoxy dinitriles from citral and their acid-catalyzed transformations

Synthesis of epoxy dinitriles from citral and their acid-catalyzed transformations Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2007, Volume: 43, Number: 4, Pages: 511-517 Pages count : 7 DOI: 10.1134/S1070428007040045

Authors

Volcho K.P. , Yarovaya O.I. , Kurbakova S.Yu. , Korchagina D.V. , Barkhash V.A. , Salakhutdinov N.F.

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

2,3-and 6,7-Epoxy derivatives of citral react with malononitrile in the presence of basic Cs beta-zeolite to give the corresponding epoxyalkenylidenemalononitriles as the major products. Epoxy dinitriles obtained from 6,7-epoxycitral undergo acid-catalyzed transformations into tetrahydrofuran derivatives or acyclic polyenes containing hydroxy and cyano groups, depending on the catalyst nature.

Volcho K.P. , Yarovaya O.I. , Kurbakova S.Y. , Korchagina D.V. , Barkhash V.A. , Salakhutdinov N.F.
Synthesis of epoxy dinitriles from citral and their acid-catalyzed transformations
Russian Journal of Organic Chemistry. 2007. V.43. N4. P.511-517. DOI: 10.1134/S1070428007040045 WOS Scopus РИНЦ

Волчо К.П. , Яровая О.И. , Курбакова С.Ю. , Корчагина Д.В. , Бархаш В.А. , Салахутдинов Н.Ф.
Получение из цитраля эпоксидинитрилов и их кислотно-катализируемые превращения
Журнал органической химии (RUSS J ORG CHEM+). 2007. Т.43. №4. С.514-520. РИНЦ

Published print:

Apr 1, 2007

Web of science	WOS:000246525700004
Scopus	2-s2.0-34248586956
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