Synthesis and properties of copper(II) complexes with a chiral dioxatetraazamacrocyclic ligand based on a natural monoterpene, (+)-3-carene

Synthesis and properties of copper(II) complexes with a chiral dioxatetraazamacrocyclic ligand based on a natural monoterpene, (+)-3-carene Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236

Output data

Year: 2007, Volume: 52, Number: 1, Pages: 42-45 Pages count : 4 DOI: 10.1134/S0036023607010081

Authors

Larionov S.V. ¹ , Myachina L.I. ¹ , Sheludyakova L.A. ¹ , Boguslavskii E.G. ¹ , Bizyaev S.N. ² , Tkachev A.V. ²

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

The copper(II) compounds [CuL](NO3)(2) center dot H2O (I), [CuL](ClO4)(2) center dot H2O (II), CuLCl2 center dot 3H(2)O (III), and CuLBr2 center dot 4H(2)O (IV), where L is a chiral dioxatetraazamacrocyclic ligand based on the natural monoterpene (+)-3-carene, have been synthesized. According to IR and EPR spectroscopy, L acts as a tetradentate chelating ligand coordinated through the N atoms of the NH and C=N groups. The NO3- anions in I and the ClO4- anions in II are outer-sphere. I and II have a planar coordination core CuN4, III has a CuN4ClO coordination core, and IV has a CuN4Br2 coordination core.

Larionov S.V. , Myachina L.I. , Sheludyakova L.A. , Boguslavskii E.G. , Bizyaev S.N. , Tkachev A.V.
Synthesis and properties of copper(II) complexes with a chiral dioxatetraazamacrocyclic ligand based on a natural monoterpene, (+)-3-carene
Russian Journal of Inorganic Chemistry. 2007. V.52. N1. P.42-45. DOI: 10.1134/S0036023607010081 WOS Scopus РИНЦ

Ларионов С.В. , Мячина Л.И. , Шелудякова Л.А. , Богуславский Е.Г. , Бизяев С.Н. , Ткачев А.В.
СИНТЕЗ И СВОЙСТВА КООРДИНАЦИОННЫХ СОЕДИНЕНИЙ МЕДИ(II) С ХИРАЛЬНЫМ ДИОКСАТЕТРААЗАМАКРОЦИКЛИЧЕСКИМ ЛИГАНДОМ НА ОСНОВЕ ПРИРОДНОГО МОНОТЕРПЕНА (+)-3-КАРЕНА
Журнал неорганической химии. 2007. Т.52. №1. С.47-50. РИНЦ

Published print:

Jan 1, 2007

Web of science	WOS:000245665700008
Scopus	2-s2.0-33846704939
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