Abstract: The synthesis of the [Cu(H2L)](NO3)(2) complex (I) and of a mixed-valent complex [Cu(H2L)Cl](2)[CuCl2]Cl center dot 0.5H(2)O (II), where L is chiral bis(menthane) propylenediaminodioxime. According to the data of single-crystal X-ray diffraction analysis, compounds I and 11 have ionic structures. In complex cations, the Cu2+, ion coordinates four N atoms of tetradentate chelate ligand, namely, the H2L molecule. The coordination surrounding of the Cu atom in I is a distorted square CuN4, while in 11, it is a distorted square in 11 has linear structure. The mutual arrangement of oxime pyramid CuN4Cl. The complex anion [CuCl2](-) groups in H2L corresponds to amphi-configuration of a ligand and therefore, intramolecular hydrogen bond O center dot center dot center dot H-O are formed in H2L. The complex cations in compound II are joined in dimers through hydrogen bonds Cl center dot center dot center dot H-O. The values mu(eff) for I and II are equal to 1.82 and 2.82 mu(B), respectively.

Cite: Savel'eva Z.A. , Klevtsova R.F. , Glinskaya L.A. , Ikorskii V.N. , Bizyaev S.N. , Tkachev A.V. , Larionov S.V.
Complexes [Cu(H2L)](NO3)(2) and [Cu(H2L)Cl](2)[CuCl2]Cl center dot 0.5H(2)O (H2L is chiral bis(menthane) propylenediaminodioxime): Synthesis and structure
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2006. V.32. N11. P.784-791. DOI: 10.1134/S1070328406110030 WOS Scopus РИНЦ

ArticleLinkType.TRANSLATED_TO_ORIGINAL: Савельева З.А. , Клевцова Р.Ф. , Глинская Л.А. , Икорский В.Н. , Бизяев С.Н. , Ткачев А.В. , Ларионов С.В.
Синтез и строение соединений [Cu(H2L)](NO3)2 и [Cu(H2L)Cl]2[CuCl2]Cl 0.5H2O, гдеH2L - хиральный бис(ментановый) пропилендиаминодиоксим
Координационная химия (RUSS J COORD CHEM+). 2006. Т.32. №11. С.816-823. РИНЦ

Dates:

Published print:

Nov 1, 2006

Identifiers:

Web of science	WOS:000242235300003
Scopus	2-s2.0-33750914869
Elibrary	13517929
OpenAlex	W2014607939

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