Ni(II) complexes with optically active bis(menthane), pinano-para-menthane ethylenediaminodioximes and pinano-para-menthane, bis(pinane) propylenediaminodioximes: Synthesis, structures, and properties

Ni(II) complexes with optically active bis(menthane), pinano-para-menthane ethylenediaminodioximes and pinano-para-menthane, bis(pinane) propylenediaminodioximes: Synthesis, structures, and properties Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2006, Volume: 32, Number: 10, Pages: 723-732 Pages count : 10 DOI: 10.1134/S1070328406100058

Authors

Savel'eva Z.A. , Bizyaev S.N. , Glinskaya L.A. , Klevtsova R.F. , Tkachev A.V. , Larionov S.V.

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

Reactions of Ni(NO3)(2) center dot 6H(2)O) in EtOH(iso-PrOH) with optically active bis(menthane) ethylenediaminodioxime (H2L1), pinano-para-menthane ethylenediaminodioxime (H2L2), pinano-para-menthane propylenediaminodioxime (H2L3) and bis(pinane) propylenediaminodioxime (H2L4) were used to synthesize [Ni(H2L1)NO3]NP3 center dot 2H(2)O (I), [Ni(HL2)]NO3 (II), [Ni(HL3)]NO3 (III), and [Ni(HL4)]NO3 (IV). X-ray diffraction study of paramagnetic complex I (mu(eff) = 3.04 mu B and diamagnetic complexes II and III revealed their ionic structures. A distorted octahedral polyhedron N4O2 in the cation of complex I is formed by the N atoms of tetradentate cycle-forming ligand, i.e., the H2L1 molecule, and the O atoms of the NO3- anion acting as a bidentate cyclic ligand. In the cations of complexes H and III, containing a pinane fragment, the coordination core NiN4 has the shape of a distorted square formed on coordination of tetradentate cycle-forming ligands, i.e., anions of the starting dioximes. The structure of diamagnetic complex IV is likely to be similar to the structures of complexes II and III.

Savel'eva Z.A. , Bizyaev S.N. , Glinskaya L.A. , Klevtsova R.F. , Tkachev A.V. , Larionov S.V.
Ni(II) complexes with optically active bis(menthane), pinano-para-menthane ethylenediaminodioximes and pinano-para-menthane, bis(pinane) propylenediaminodioximes: Synthesis, structures, and properties
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2006. V.32. N10. P.723-732. DOI: 10.1134/S1070328406100058 WOS Scopus РИНЦ

Савельева З.А. , Бизяев С.Н. , Глинская Л.А. , Клевцова Р.Ф. , Ткачев А.В. , Ларионов С.В.
Синтез, структура и свойства комплексов никеля(ii) с оптически активными бис(ментановым), пинано-пара-ментановым этилендиаминодиоксимами и пинано-ашра-ментановым, бис(пинановым) пропилендиаминодиоксимами
Координационная химия (RUSS J COORD CHEM+). 2006. Т.32. №10. С.754-763. РИНЦ

Published print:

Oct 1, 2006

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