Kinetics of the reaction of 4-nitrophenyl benzoates with 4-chlorophenol in the presence of potassium carbonate in dimethylformamide

Kinetics of the reaction of 4-nitrophenyl benzoates with 4-chlorophenol in the presence of potassium carbonate in dimethylformamide Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2006, Volume: 42, Number: 6, Pages: 865-872 Pages count : 8 DOI: 10.1134/S1070428006060091

Authors

Os'kina I.A. ¹ , Vlasov V.M. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The effect of the substituent in the benzoyl group on the relative rate and activation parameters of transesterification of substituted 4-nitrophenyl benzoates with 4-chlorophenol in dimethylformamide in the presence of potassium carbonate was studied by the competing reaction technique. The whole series of benzoates showed the enthalpy-entropy compensation effect. 4-Nitrophenyl benzoates having electron-acceptor substituents give rise to isokinetic relationship with an isokinetic temperature beta of 382 K. The mechanism of the transesterification process is discussed.

Os'kina I.A. , Vlasov V.M.
Kinetics of the reaction of 4-nitrophenyl benzoates with 4-chlorophenol in the presence of potassium carbonate in dimethylformamide
Russian Journal of Organic Chemistry. 2006. V.42. N6. P.865-872. DOI: 10.1134/S1070428006060091 WOS Scopus РИНЦ

Оськина И.А. , Власов В.М.
Кинетика реакции 4-нитрофенил-бензоатов с 4-хлорфенолом в присутствии карбоната калия в диметилформ-амиде
Журнал органической химии (RUSS J ORG CHEM+). 2006. Т.42. №6. С.886-893. РИНЦ

Published print:

Jun 1, 2006

Web of science	WOS:000239375600009
Scopus	2-s2.0-33745967717
Elibrary	13519181
OpenAlex	W2055771632