Photochemistry of 1,3,2,4-benzodithiadiazines: formation and oxidation of 1,2,3-benzodithiazolyl radicals

Photochemistry of 1,3,2,4-benzodithiadiazines: formation and oxidation of 1,2,3-benzodithiazolyl radicals Full article

Journal

Photochemical and Photobiological Sciences
ISSN: 1474-905X , E-ISSN: 1474-9092

Output data

Year: 2006, Volume: 5, Number: 1, Pages: 95-101 Pages count : 7 DOI: 10.1039/b510188c

Authors

Gritsan N.P. ^1,2 , Kim S.N. ^1,3 , Makarov A.Yu. ⁴ , Chesnokova E.N. ¹ , Zibarev A.V. ^2,4

Affiliations

1	(Данные Web of science) Russian Acad Sci, Inst Chem Kinet & Combust, Siberian Branch, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Dept Phys, Novosibirsk 630090, Russia
3	(Данные Web of science) Russian Acad Sci, Dept Nat Sci, Novosibirsk 630090, Russia
4	(Данные Web of science) Russian Acad Sci, Inst Organ Chem, Siberian Bran

Photolysis of 1,3,2,4-benzodithiadiazine and its derivatives in hydrocarbon solutions yields dinitrogen and stable 1,2,3-benzodithiazolyls ( Herz radicals) whose interaction with dioxygen leads finally to O=S=N-substituted diphenyl disulfides via a self termination-like process with an effective second-order rate constant depending linearly on the concentration of dissolved O-2.

Gritsan N.P. , Kim S.N. , Makarov A.Y. , Chesnokova E.N. , Zibarev A.V.
Photochemistry of 1,3,2,4-benzodithiadiazines: formation and oxidation of 1,2,3-benzodithiazolyl radicals
Photochemical and Photobiological Sciences. 2006. V.5. N1. P.95-101. DOI: 10.1039/b510188c WOS Scopus РИНЦ

Web of science	WOS:000237106100012
Scopus	2-s2.0-33645525826
Elibrary	13529715
OpenAlex	W2112001639