Reactions of perfluorinated 1-ethyltetrahydronaphthalene, 1-ethylindan, and 1,1-diethylindan with pentafluorobenzene in antimony pentafluoride

Reactions of perfluorinated 1-ethyltetrahydronaphthalene, 1-ethylindan, and 1,1-diethylindan with pentafluorobenzene in antimony pentafluoride Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2006, Volume: 42, Number: 1, Pages: 77-86 Pages count : DOI: 10.1134/S1070428006010131

Authors

Sinyakov VR , Mezhenkova TV , Karpov VM , Platonov VE , Rybalova TV , Gatilov YV

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The reaction of perfluoro(1-ethyltetrahydronaphthalene) with pentafluorobenzene in SbF5, followed by treatment of the reaction mixture with water, afforded a mixture of 1-hydroxyperfluoro(1-phenyl-4-ethyltetrahydronaphthalene) and perfluoro(5-phenyl-8-ethyl-2,6,7,8-tetrahydronaphthalen-2-one). From perfluoro(1,1-diethylindan). 1-hydroxyperfluoro(1,1-diethyl-3-phenylindan) was obtained. Perfluoro(1-ethylindan) reacted with an equimolar amount of pentafluorobenzene in SbF5 to give (after hydrolysis) 1-hydroxyperfluoro(3-ethyl-1-phenylindan), 1-hydroxyperfluoro(3-ethyl-1,3-diphenylindan), and perfluoro(1-ethyl-1-phenyl-indan), while in the reaction with excess pentafluorobenzene, followed by treatment with anhydrous hydrogen fluoride, perfluoro(1-ethyl-3-phenyl-indan) and perfluoro(1-ethyl-1,3-diphenylindan)were formed.

Sinyakov V. , Mezhenkova T. , Karpov V. , Platonov V. , Rybalova T. , Gatilov Y.
Reactions of perfluorinated 1-ethyltetrahydronaphthalene, 1-ethylindan, and 1,1-diethylindan with pentafluorobenzene in antimony pentafluoride
Russian Journal of Organic Chemistry. 2006. V.42. N1. P.77-86. DOI: 10.1134/S1070428006010131 WOS Scopus РИНЦ

Синяков В.Р. , Меженкова Т.В. , Карпов В.М. , Платонов В.Е. , Рыбалова Т.В. , Гатилов Ю.В.
ВЗАИМОДЕЙСТВИЕ ПЕРФТОРИРОВАННЫХ 1-ЭТИЛТЕТРАЛИНА, 1-ЭТИЛ- И 1,1-ДИЭТИЛ-ИНДАНОВ С ПЕНТАФТОРБЕНЗОЛОМ В СРЕДЕ SBF5
Журнал органической химии (RUSS J ORG CHEM+). 2006. Т.42. №1. С.85-93. РИНЦ

Published print:

Jan 1, 2006

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