Synthesis and crystal and molecular structure of the [Co(HL)Cl-2] complex (H2L is an optically active terpene bis-pinane propylenediaminodioxime)

Synthesis and crystal and molecular structure of the [Co(HL)Cl-2] complex (H2L is an optically active terpene bis-pinane propylenediaminodioxime) Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2005, Volume: 46, Number: 3, Pages: 546-550 Pages count : 5 DOI: 10.1007/s10947-006-0137-7

Tags

Co(III) complex; terpene; propylenediaminodioxime; chirality; crystal structure

Authors

Larionov S.V. , Savelieva Z.A. , Glinskaya L.A. , Klevtsova R.F. , Bizyaev S.N. , Tkachev A.V.

Affiliations

1	(Данные Web of science) Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, NN Vorozhtsov Novosibirsk Inst Organ Chem, Moscow 117901, Russia

Interaction of Co(II) chloride with optically active bis-pinane propylenediaminodioxime (H2L) gave a diamagnetic compound of Co(III) with a composition [Co(HL)Cl-2]. The crystal and molecular structure of the compound was determined by X-ray diffraction (XRD) analysis (Enraf-Nonius CAD-4 diffractometer, lambda MoK alpha, 703 F-hkl, R = 0.0347). The crystals are orthorhombic with unit cell parameters a = 8.989(1) angstrom, b = 12.351(2) angstrom, c = 22.425(3) angstrom, V = 2487.7(6) angstrom(3), Z = 4, rho(calc) = 1.420 g/cm(3), space group P2(1)2(1)2(1). The crystal structure of the complex is composed of discrete one-center molecules. In the complex, the Co3+ ion coordinates four N atoms of the tetradentate cycle-forming ligand (HL- anion) and two Cl atoms. The coordination polyhedron of Co is a distorted octahedron Cl2N4.

Larionov S.V. , Savelieva Z.A. , Glinskaya L.A. , Klevtsova R.F. , Bizyaev S.N. , Tkachev A.V.
Synthesis and crystal and molecular structure of the [Co(HL)Cl-2] complex (H2L is an optically active terpene bis-pinane propylenediaminodioxime)
Journal of Structural Chemistry. 2005. V.46. N3. P.546-550. DOI: 10.1007/s10947-006-0137-7 WOS Scopus РИНЦ

Ларионов С.В. , Савельева З.А. , Глинская Л.А. , Клевцова Р.Ф. , Бизяев С.Н. , Ткачев А.В.
Синтез, кристаллическая и молекулярная структура комплекса [CO(HL)CL2] (H2L - оптически активный терпеновый бис-пинановый пропилендиаминодиоксим)
Журнал структурной химии (J STRUCT CHEM+). 2005. Т.46. №3. С.558-563. РИНЦ

Published print:

May 1, 2005

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