Synthesis and structure of optically active compounds [Ni(HL1)]NO3 and [Ni(HL2)]NO3 center dot H2O containing anions of diaminodioximes H2L1 and H2L2 derived from alpha-pinene and (+)-3-carene as ligands

Synthesis and structure of optically active compounds [Ni(HL1)]NO3 and [Ni(HL2)]NO3 center dot H2O containing anions of diaminodioximes H2L1 and H2L2 derived from alpha-pinene and (+)-3-carene as ligands Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2004, Volume: 30, Number: 12, Pages: 837-845 Pages count : 9 DOI: 10.1007/s11173-005-0018-1

Authors

Larionov S.V. ¹ , Myachina L.I. ¹ , Savel'eva Z.A. ¹ , Glinskaya L.A. ¹ , Klevtsova R.F. ¹ , Sheludyakova L.A. ¹ , Tkachev A.V. ² , Bizyaev S.N. ²

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, 630090, Novosibirsk, Russia
2	Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

New optically active levorotatory compounds [Ni(HL1)]NO3 (1) and [Ni(HL2)]NO3 (.) H2O (II) containine, the anions of chiral diaminodioximes, H2L1 and H2L2, derived from the terpenes alpha-pinene and (+)-3-carene, respectively, were synthesized. Complexes I and II were studied by X-ray diffraction. The crystal structures of compounds are ionic, being composed of the [Ni(HL1)](+) or [Ni(HL2)](+) cations and the outer-sphere NO3- anions. The Ni2+ ion coordinates four N atoms of the tetradentate chelating ligand, the NiN4 coordination unit being shaped like a tetrahedrally distorted square. Compounds I and 11 are diamagnetic, which corresponds to a low-spin d(8) configuration. The NMR spectra of compounds were recorded and analyzed.

Larionov S.V. , Myachina L.I. , Savel'eva Z.A. , Glinskaya L.A. , Klevtsova R.F. , Sheludyakova L.A. , Tkachev A.V. , Bizyaev S.N.
Synthesis and structure of optically active compounds [Ni(HL1)]NO3 and [Ni(HL2)]NO3 center dot H2O containing anions of diaminodioximes H2L1 and H2L2 derived from alpha-pinene and (+)-3-carene as ligands
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2004. V.30. N12. P.837-845. DOI: 10.1007/s11173-005-0018-1 WOS Scopus РИНЦ

Ларионов С.В. , Мячина Л.И. , Савельева З.А. , Глинская Л.А. , Клевцова Р.Ф. , Шелудякова Л.А. , Ткачев А.В. , Бизяев С.Н.
СИНТЕЗ И СТРУКТУРА ОПТИЧЕСКИ АКТИВНЫХ СОЕДИНЕНИЙ [NI(HL 1)]NO 3 И [NI(HL 2)]NO 3 · H 2O, СОДЕРЖАЩИХ ЛИГАНДЫ-АНИОНЫ ДИАМИНОДИОКСИМОВ H 2L 1, H 2L 2 - ПРОИЗВОДНЫХ α-ПИНЕНА И (+)-3-КАРЕНА
Координационная химия (RUSS J COORD CHEM+). 2004. Т.30. №12. С.888-896. РИНЦ

Published print:

Dec 1, 2004

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