Synthesis and structure of copper(II) complexes with diaminodioxime (H2L), a derivative of the monoterpenoid (+)-3-carene

Synthesis and structure of copper(II) complexes with diaminodioxime (H2L), a derivative of the monoterpenoid (+)-3-carene Full article

Journal

Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284

Output data

Year: 2004, Volume: 30, Number: 12, Pages: 846-849 Pages count : 4 DOI: 10.1007/s11173-005-0022-5

Authors

Larionov SV , Myachina LI , Sheludyakova LA , Boguslavskii EG , Tkachev AV , Bizyaev SN

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

Copper(II) compounds with the optically active diaminodioxime (H2L) derived from the monoterpenoid (+)-3-carene, Cu(H2L)(NO3)(2) (.) H2O (I), Cu(H2L)(ClO4)(2) (.) H2O (II), Cu(H2L)Br-2 (.) H2O (III), and Cu(H2L)SO4 (.) 0.5H(2)O (IV) with mu(eff) equal to 1.81, 1.79, 1.71, and 1.8 mu(B), respectively, were prepared. Studies of the complexes by IR and EPR spectroscopy showed that I and II are mononuclear ionic complexes. Compound III apparently has polymeric structure (the CuN4Br2 coordination unit). According to EPR data, the Cu2+ ions in polycrystalline compounds III and IV undergo exchange interactions.

Larionov S. , Myachina L. , Sheludyakova L. , Boguslavskii E. , Tkachev A. , Bizyaev S.
Synthesis and structure of copper(II) complexes with diaminodioxime (H2L), a derivative of the monoterpenoid (+)-3-carene
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2004. V.30. N12. P.846-849. DOI: 10.1007/s11173-005-0022-5 WOS Scopus РИНЦ

Ларионов С.В. , Мячина Л.И. , Шелудякова Л.А. , Богуславский Е.Г. , Ткачев А.В. , Бизяев С.Н.
СИНТЕЗ И СТРОЕНИЕ КОМПЛЕКСОВ МЕДИ(II) С ДИАМИНОДИОКСИМОМ (H 2L) - ПРОИЗВОДНЫМ МОНОТЕРПЕНОИДА (+)-3-КАРЕНА
Координационная химия (RUSS J COORD CHEM+). 2004. Т.30. №12. С.897-900. РИНЦ

Published print:

Dec 1, 2004

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