Dehalogenative aromatization of perchlorofluoroalicyclic compounds C6Cl6F6, C10Cl8F8 and C5Cl4F5N in the vapour phase or in solution

Dehalogenative aromatization of perchlorofluoroalicyclic compounds C6Cl6F6, C10Cl8F8 and C5Cl4F5N in the vapour phase or in solution Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2004, Volume: 125, Number: 10, Pages: 1431-1435 Pages count : DOI: 10.1016/j.jfluchem.2004.04.015

Tags

dehalogenation; hexafluorobenzene; octafluoronaphthalene; pentafluoropyridine

Authors

Bardin VV , Trukhin DV , Adonin NY , Starichenko VF

Affiliations

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, SB, Novosibirsk 630090, Russia

Dehalogenation of perhalogenated cyclohexanes C6Cl6F6, 1-azacyclohexenes C5Cl4F5N and bicyclo[4.4.0]dec-1(6)-enes C10Cl8F8 in the vapour phase over iron filings at 350-500 degreesC and in solution with Zn and additivities (Cu, NiCl2.6H(2)O + bpy) at 80 degreesC (heterogeneous reaction) or with P(NEt2)(3) at 20 degreesC (homogeneous reaction) was studied. In all cases, perfluoroarenes, chloroperfluoroarenes and dichloroperfluoroarenes (benzenes, naphthalenes and pyridines) were obtained in good overall yield. (C) 2004 Elsevier B.V. All rights reserved.

Bardin V. , Trukhin D. , Adonin N. , Starichenko V.
Dehalogenative aromatization of perchlorofluoroalicyclic compounds C6Cl6F6, C10Cl8F8 and C5Cl4F5N in the vapour phase or in solution
Journal of Fluorine Chemistry. 2004. V.125. N10. P.1431-1435. DOI: 10.1016/j.jfluchem.2004.04.015 WOS Scopus РИНЦ

Published print:

Oct 1, 2004

Web of science	WOS:000224445400005
Scopus	2-s2.0-4644281650
Elibrary	13473421
OpenAlex	W1965891959