Synthesis and molecular and crystalline structure of polyfluoro-1,3-diazafluorenes

Synthesis and molecular and crystalline structure of polyfluoro-1,3-diazafluorenes Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2004, Volume: 40, Number: 3, Pages: 421-425 Pages count : 5 DOI: 10.1023/B:RUJO.0000034983.96937.18

Authors

Karpov VM ¹ , Platonov VE ¹ , Chuikov IP ¹ , Rybalova TV ¹ , Gatilov YV ¹ , Shakirov MM ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Div, Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Reactions of 2-amino-3-(1-imino-2,2,2-trifluoroethyl)hexafluoro-1H-indene with carboxylic acid anhydrides and chlorides afforded 2-alkyl(aryl)-4-trifluoromethyl-5,6,7,8,9,9-hexafluoro-1,3-diazafluorenes. The molecular and crystalline structure of the products was studied by NMR spectroscopy and X-ray diffraction. 5,6,7,8,9,9-Hexafluoro-2-phenyl-4-trifluoromethyl-1,3-diazafluorene in crystal gives rise to infinite ladder chains via :tau-stacking interaction between the benzene ring of one molecule and tetrafluoro benzene fragment of the other.

Karpov V. , Platonov V. , Chuikov I. , Rybalova T. , Gatilov Y. , Shakirov M.
Synthesis and molecular and crystalline structure of polyfluoro-1,3-diazafluorenes
Russian Journal of Organic Chemistry. 2004. V.40. N3. P.421-425. DOI: 10.1023/B:RUJO.0000034983.96937.18 WOS Scopus РИНЦ

Карпов В.М. , Платонов В.Е. , Чуйков И.П. , Рыбалова Т.В. , Гатилов Ю.В. , Шакиров М.М.
Синтез, молекулярная и кристаллическая структура полифтор-1,з-диазафлуоренов
Журнал органической химии (RUSS J ORG CHEM+). 2004. Т.40. №3. С.448-452. РИНЦ

Published print:

Mar 1, 2004

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