Efficient synthesis of salts of the tetrakis(perfluoroorgano)borate anion, [B(CF=CF2)(4)](-)

Efficient synthesis of salts of the tetrakis(perfluoroorgano)borate anion, [B(CF=CF2)(4)](-) Full article

Journal

Organometallics
ISSN: 0276-7333

Output data

Year: 2004, Volume: 23, Number: 2, Pages: 172-174 Pages count : DOI: 10.1021/om030610i

Authors

Adonin NY , Bardin VV , Florke U , Frohn HJ

Affiliations

1	(Данные Web of science) Univ Duisburg Gesamthsch, Inst Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) RAS, SB, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
3	(Данные Web of science) Univ Gesamthsch Paderborn, Dept Chem, D-33098 Paderborn, Germany

The synthesis and the NMR spectra of the tetrakis(trifluorovinyl)borate salts M[B(CF CF2)(4)] (M = Li, K, Cs, [(NRR32)-R-1]) as well as the X-ray crystal structure of the tetramethylammonium salt are reported. These salts were prepared by the reaction of boron trichloride with bis(trifluorovinyl)di-n-butyltin in the presence of tri- and tetraalkylammonium or alkali-metal chlorides in dichloromethane.

Adonin N. , Bardin V. , Florke U. , Frohn H.
Efficient synthesis of salts of the tetrakis(perfluoroorgano)borate anion, [B(CF=CF2)(4)](-)
Organometallics. 2004. V.23. N2. P.172-174. DOI: 10.1021/om030610i WOS Scopus

Published online:	Dec 12, 2003
Published print:	Jan 1, 2004

Web of science	WOS:000188083900006
Scopus	2-s2.0-0942299071
OpenAlex	W2033594516