The alicyclic ring contraction of perfluoro-1-phenyltetralin in reaction with antimony pentafluoride

The alicyclic ring contraction of perfluoro-1-phenyltetralin in reaction with antimony pentafluoride Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2004, Volume: 125, Number: 1, Pages: 49-53 Pages count : 5 DOI: 10.1016/j.jfluchem.2003.09.006

Tags

skeletal transformations; perfluorophenyltetralin; alicyclic ring contraction; antimony pentafluoride; NMR spectroscopy

Authors

Sinyakov VR , Mezhenkova TV , Karpov VM , Platonov VE

Affiliations

1	(Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Perfluoro-1-phenyltetralin (1) heated with antimony pentafluoride at 130 degreesC, then treated with water, gave a mixture of perfluorinated 3-methyl-2-phenylindenone (3), 3-methyl-2-phenylindene (4), 3-hydroxy-1-methyl-3-phenylindan (5), 1-methyl-3-phenylindan (6), 9-methyl-1,2,3,4,5,6,7,8-octahydroanthracene (7), and 1,9-dimethyl-5,6,7,8-tetrahydro-beta-naphthindan (8). When heated with SbF5 in the presence of HF, then treated with water, compound 1 is transformed to a mixture of products 3-6. The reaction at 170 and 200 degreesC forms compounds 3-6 together with perfluoro-2-(cyclohexen-1-yl)-3-methylindene (10). (C) 2003 Elsevier B.V. All rights reserved.

Sinyakov V. , Mezhenkova T. , Karpov V. , Platonov V.
The alicyclic ring contraction of perfluoro-1-phenyltetralin in reaction with antimony pentafluoride
Journal of Fluorine Chemistry. 2004. V.125. N1. P.49-53. DOI: 10.1016/j.jfluchem.2003.09.006 WOS Scopus РИНЦ

Published print:

Jan 1, 2004

Web of science	WOS:000188380000007
Scopus	2-s2.0-0347022589
Elibrary	13451456
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