The stereospecific substitution of the xenon atom in cis-perfluoroalk-1-enylxenon(II) salts by hydrogen, halogens, and the phenyl group

The stereospecific substitution of the xenon atom in cis-perfluoroalk-1-enylxenon(II) salts by hydrogen, halogens, and the phenyl group Full article

Journal

Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313

Output data

Year: 2004, Volume: 630, Number: 7, Pages: 1022-1024 Pages count : DOI: 10.1002/zaac.200400056

Tags

noble gas chemistry; xenon-carbon compounds; perfluoroalk-1-enylation reactions; stereochemistry

Authors

Frohn HJ , Bardin VV

Affiliations

1	(Данные Web of science) Univ Duisburg, Anorgan Chem Inst Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) SB RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk, Russia

The substitution of the xenon atom in reactions of [cis-CnF2+1CF=CFXe][Y] salts with benzene, iodide, and bromide anions in propionitrile solution by the phenyl group, or iodine, and bromine atoms, respectively, occurred stereospecifically. When a propionitrile solution of [cis-C2F5CF=CFXe][AsF6] was kept at -40 degreesC without an additional reactant, the fluoroalkene cis-C2F5CF=CFH was the only isomer obtained.

Frohn H. , Bardin V.
The stereospecific substitution of the xenon atom in cis-perfluoroalk-1-enylxenon(II) salts by hydrogen, halogens, and the phenyl group
Zeitschrift fur Anorganische und Allgemeine Chemie. 2004. V.630. N7. P.1022-1024. DOI: 10.1002/zaac.200400056 WOS Scopus РИНЦ

Published print:

Jul 1, 2004

Web of science	WOS:000222967800011
Scopus	2-s2.0-4644252703
Elibrary	13461676
OpenAlex	W2150130117