The reaction of 2-X-1,2-difluoroalk-1-enyldifluoroboranes with xenon difluoride. A methodical approach to 1,2-difluoroalk-1-enylxenon(II) salts

The reaction of 2-X-1,2-difluoroalk-1-enyldifluoroboranes with xenon difluoride. A methodical approach to 1,2-difluoroalk-1-enylxenon(II) salts Full article

Journal

Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313

Output data

Year: 2003, Volume: 629, Number: 14, Pages: 2499-2508 Pages count : 10 DOI: 10.1002/zaac.200300234

Tags

noble gas chemistry; xenon-carbon compounds; polyfluoroalkenylboranes; xenodeborylation; polyfluoroalkylborate anions; NMR spectroscopy

Authors

Frohn HJ ¹ , Adonin NY ² , Bardin VV ²

Affiliations

1	(Данные Web of science) Univ Duisburg Gesamthsch, Inst Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, SB, Novosibirsk, Russia

2-X-1,2-Difluoroalk-1-enylxenon(II) salts were prepared by the reaction of XeF2 with XCF=CFBF2 (X = F, trans-H, cis-Cl, trans-Cl, cis-CF3, cis-C2F5) but no organoxenon(II) compounds were obtained when the trans-isomers of boranes, trans-XCF=CFBF2, (X = CF3, C4F9, C4H9, Et3Si), were used under similar conditions.

Frohn H. , Adonin N. , Bardin V.
The reaction of 2-X-1,2-difluoroalk-1-enyldifluoroboranes with xenon difluoride. A methodical approach to 1,2-difluoroalk-1-enylxenon(II) salts
Zeitschrift fur Anorganische und Allgemeine Chemie. 2003. V.629. N14. P.2499-2508. DOI: 10.1002/zaac.200300234 WOS Scopus РИНЦ

Published print:

Dec 1, 2003

Web of science	WOS:000188203600016
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