Trifluoropropynylxenon(II) tetrafluoroborate [CF3C CXe] [BF4] - isolation of an alkynylxenon(II) compound for the first time

Trifluoropropynylxenon(II) tetrafluoroborate [CF3C CXe] [BF4] - isolation of an alkynylxenon(II) compound for the first time Full article

Journal

Chemical Communications
ISSN: 1359-7345

Output data

Year: 2003, Number: 18, Pages: 2352-2353 Pages count : 2 DOI: 10.1039/b307583d

Authors

Frohn HJ ¹ , Bardin VV ²

Affiliations

1	(Данные Web of science) Univ Duisburg Essen, Inst Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) SB RAS, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

The salt [CF(3)Cequivalent toCXe] [BF4] was prepared as neat compound by the reaction of the hitherto unknown alkynyldifluoroborane CF(3)Cequivalent toCBF(2) with XeF2 in 1,1,1,3,3-pentafluoropropane (PFP) at -45 degreesC in 59% yield. [CF(3)Cequivalent toCXe] [BF4] was unambiguously characterised by multinuclear NMR spectroscopy in anhydrous HF (aHF) solution.

Frohn H. , Bardin V.
Trifluoropropynylxenon(II) tetrafluoroborate [CF3C CXe] [BF4] - isolation of an alkynylxenon(II) compound for the first time
Chemical Communications. 2003. N18. P.2352-2353. DOI: 10.1039/b307583d WOS Scopus РИНЦ

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