Reaction of nitrosonium tetrafluoroborate with nitroxyl radicals

Reaction of nitrosonium tetrafluoroborate with nitroxyl radicals Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2003, Volume: 39, Number: 8, Pages: 1144-1150 Pages count : 7 DOI: 10.1023/B:RUJO.0000010183.47456.c4

Authors

Borodkin GI ¹ , Elanov IR ¹ , Shakirov MM ¹ , Shubin VG ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

It was established by means of multinuclear magnetic resonance method (H-1, C-13, F-19 and N-14) that reaction of 2,2,6,6-tetramethyl-4-R-piperidin-1-oxyl radicals (R = H, OH, OMe, OCOPh, NHCOMe) with nitrosonium tetrafluoroborate gave rise to the corresponding 2,2,6,6-tetramethyl-1-oxo-4-R-piperidinium tetrafluoroborates. Linear correlations were found between the chemical shifts of atoms H-4, C-4 of cations and respectively sigma(1)-constants of substituents R and chemical shifts of C-4 atom calculated from increments of substitution. The conformational features of the generated nitrosonium cations are considered on the grounds of vicinal coupling constants J(HH) and quantum-chemical calculations by AM1 method.

Borodkin G. , Elanov I. , Shakirov M. , Shubin V.
Reaction of nitrosonium tetrafluoroborate with nitroxyl radicals
Russian Journal of Organic Chemistry. 2003. V.39. N8. P.1144-1150. DOI: 10.1023/B:RUJO.0000010183.47456.c4 WOS Scopus РИНЦ

Бородкин Г.И. , Еланов И.Р. , Шакиров М.М. , Шубин В.Г.
Взаимодействие тетрафторбората нитрозония с нитроксильными радикалами
Журнал органической химии (RUSS J ORG CHEM+). 2003. Т.39. №8. С.1215-1221. РИНЦ

Published print:

Aug 1, 2003

Web of science	WOS:000187622800014
Scopus	2-s2.0-3542997454
Elibrary	13426441
OpenAlex	W2022615175