Reaction of perfluoro-1-methylbenzocyclobutene with pentafluorobenzene in SbF5 medium

Reaction of perfluoro-1-methylbenzocyclobutene with pentafluorobenzene in SbF5 medium Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2003, Volume: 39, Number: 6, Pages: 837-842 Pages count : 6 DOI: 10.1023/B:RUJO.0000003162.41792.ad

Authors

Sinyakov VR ¹ , Mezhenkova TV ¹ , Karpov VM ¹ , Platonov VE ¹ , Rybalova TV ¹ , Gatilov YV ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Div, Novosibirsk 630090, Russia

A reaction of perfluoro-1-methylbenzocyclobutene with pentafluorobenzene in SbF5 medium followed by treating the reaction mixture with water gave rise to perfluoro-l-meth 1-1-phenylbenzocyclo-butene, perfluoro-1-methyl-2-phenylbenzocyclobutene, 2-hydroxyperfluoro-1-methyl-2-phenyibenzocyclo-butene, and also to small amounts of 1-(2-trifluoromethyltetrafluorophenyl)-1-pentafluorophenyl-2,2,2-trifluoroethane, and perfluoro-1-(2-methylphenyl)-1-phenylethylene. In a crystal of (E)-2-hydroxyperfluoro-1-methyl-2-phenylbenzocyclobutene for a dimer molecular pair a pi-stacking interaction between pentafluorophenyl groups was found.

Sinyakov V. , Mezhenkova T. , Karpov V. , Platonov V. , Rybalova T. , Gatilov Y.
Reaction of perfluoro-1-methylbenzocyclobutene with pentafluorobenzene in SbF5 medium
Russian Journal of Organic Chemistry. 2003. V.39. N6. P.837-842. DOI: 10.1023/B:RUJO.0000003162.41792.ad WOS Scopus РИНЦ

Синяков В.Р. , Меженкова Т.В. , Карпов В.М. , Платонов В.Е. , Рыбалова Т.В. , Гатилов Ю.В.
Взаимодействие перфтор-1 -метилбензоциклобутена с пентафторбензолом в среде sbf 3
Журнал органической химии (RUSS J ORG CHEM+). 2003. Т.39. №6. С.886-891. РИНЦ

Published print:

Jun 1, 2003

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