Highly efficient cross-coupling reactions with the perfluoroorganotrifluoroborate salts K [RFBF3] (RF=C6F5, CF2=CF)

Highly efficient cross-coupling reactions with the perfluoroorganotrifluoroborate salts K [RFBF3] (RF=C6F5, CF2=CF) Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039

Output data

Year: 2002, Volume: 43, Number: 45, Article number : PII S0040-4039(02)01922-6, Pages count : 4 DOI: 10.1016/S0040-4039(02)01922-6

Tags

perfluorophenyltrifluoroborate salt; perfluoroethenyltrifluoroborate salt; cross-coupling; palladium; silveroxide

Authors

Frohn HJ ¹ , Adonin NY ² , Bardin VV ² , Starichenko VF ²

Affiliations

1	(Данные Web of science) Gerhard Mercator Univ Duisburg, Inst Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) SB RAS, NV Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

Potassium pentafluorophenyl- and trifluorovinyltrifluoroborates, both containing electron-poor organo groups, reacted with iodobenzene and p-substituted iodobenzenes in the presence of palladium compounds and stoichiometric amounts of silveroxide to the fluorinated cross-coupling products in very good yields. Substituted bromobenzenes were less efficient substrates. (C) 2002 Elsevier Science Ltd. All rights reserved.

Frohn H. , Adonin N. , Bardin V. , Starichenko V.
Highly efficient cross-coupling reactions with the perfluoroorganotrifluoroborate salts K [RFBF3] (RF=C6F5, CF2=CF)
Tetrahedron Letters. 2002. V.43. N45. PII S0040-4039(02)01922-6 :1-4. DOI: 10.1016/S0040-4039(02)01922-6 WOS Scopus РИНЦ

Published print:

Nov 1, 2002

Web of science	WOS:000178774600026
Scopus	2-s2.0-0037020637
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OpenAlex	W1999459646