Molecular complexes of octafluoronaphthalene with acyclic and heterocyclic sulfur-nitrogen compounds

Molecular complexes of octafluoronaphthalene with acyclic and heterocyclic sulfur-nitrogen compounds Full article

Journal

Journal of Fluorine Chemistry
ISSN: 0022-1139

Output data

Year: 2002, Volume: 116, Number: 2, Article number : PII S0022-1139(02)00127-6, Pages count : 8 DOI: 10.1016/S0022-1139(02)00127-6

Tags

octafluoronaphthalene; sulfur-nitrogen compounds; molecular complexes; pi-stacking interactions; X-ray structure determination

Authors

Bagryanskaya IY , Gatilova YV , Lork E , Mews R , Shakirov MM , Watson PG , Zibarev AV

Affiliations

1	(Данные Web of science) Univ Bremen, Inst Inorgan & Phys Chem, D-28334 Bremen, Germany
2	(Данные Web of science) Russian Acad Sci, Inst Organ Chem, Novosibirsk 630090, Russia

Mismatched molecular 1:1 complexes were prepared from C10F8 and sulfur diimides Ar-N=S=N-Ar 1 and Ar-N=S=N-SiMe3 2, 3 (1, 2: Ar = 2,6-dimethylphenyl; 3: Ar = phenyl). In the case of 2, the complexation is accompanied by the unexpected cyclization of 2 into 7-methyl-2,1-benzisothiazole 4. The X-ray molecular structures of C10F8.1, C10F8.3 and C10F8 are presented; in C10F8.4 the 7-methyl-2,1-benzisothiazole 4 is highly disordered. The complexes provide very rare examples of markedly bent (C10F8.1), polyheteroatom (C10F8.3) and heterocyclic (C10F8.4) molecules involved in non-covalent arene-polyfluoroarene pi-stacking interactions. (C) 2002 Elsevier Science B.V. All rights reserved.

Bagryanskaya I. , Gatilova Y. , Lork E. , Mews R. , Shakirov M. , Watson P. , Zibarev A.
Molecular complexes of octafluoronaphthalene with acyclic and heterocyclic sulfur-nitrogen compounds
Journal of Fluorine Chemistry. 2002. V.116. N2. PII S0022-1139(02)00127-6 :1-8. DOI: 10.1016/S0022-1139(02)00127-6 WOS Scopus РИНЦ

Published print:

Aug 1, 2002

Web of science	WOS:000178064200009
Scopus	2-s2.0-0037189826
Elibrary	13391298
OpenAlex	W2036463175