Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its Ag-I, Au-I and Pt-II complexes

Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its Ag-I, Au-I and Pt-II complexes Full article

Journal

Mendeleev Communications
ISSN: 0959-9436

Output data

Year: 2020, Volume: 30, Number: 3, Pages: 305-307 Pages count : 3 DOI: 10.1016/j.mencom.2020.05.014

Tags

diphenyl(pyrazin-2-yl)phosphine; lithiation; pyrazine; triphenylphosphine; silver(I) complexes; gold(I) complexes; platinum(II) complexes

Authors

Rogovoy Maxim I. ¹ , Davydova Maria P. ¹ , Bagryanskaya Irina Yu. ² , Artem'ev Alexander V. ¹

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
2	(Данные Web of science) Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia

A convenient one-pot synthesis of diphenyl(pyrazin-2-yl)-phosphine has been developed based on reaction of Ph3P with metallic lithium followed by treatment of the Ph2PLi formed with 2-chloropyrazine. The Ag-I, Au-I and Pt-II chloride complexes derived from this phosphine have been synthesized and structurally characterized.

Rogovoy M.I. , Davydova M.P. , Bagryanskaya I.Y. , Artem'ev A.V.
Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its Ag-I, Au-I and Pt-II complexes
Mendeleev Communications. 2020. V.30. N3. P.305-307. DOI: 10.1016/j.mencom.2020.05.014 WOS Scopus РИНЦ

Published print:

May 1, 2020

Web of science	WOS:000539369200014
Scopus	2-s2.0-85086087628
Elibrary	43294511
OpenAlex	W3033368492