Preparation and reactivity of compounds containing a carbon-xenon bond

Preparation and reactivity of compounds containing a carbon-xenon bond Full article

Journal

Organometallics
ISSN: 0276-7333

Output data

Year: 2001, Volume: 20, Number: 23, Pages: 4750-4762 Pages count : DOI: 10.1021/om010490j

Authors

Frohn HJ , Bardin VV

Affiliations

1	(Данные Web of science) Univ Duisburg Gesamthsch, Fachgebiet Anorgan Chem, D-47048 Duisburg, Germany
2	(Данные Web of science) N N Vorozhtsov Inst Organ Chem, Novosibirsk 630090, Russia

The chemistry of carbon-xenon compounds is one of the newest in the field of organoelement chemistry. The specific character of carbon-xenon chemistry can be ascribed to the fact that in all Xe-II and Xe-IV compounds hypervalent bonds-symmetrical or asymmetrical- with a high partial positive charge on Xe are present. Different from the class of high-oxidation-state organometallic derivatives of d metals, C-Xe compounds have low coordination numbers and, additionally, contain three or two lone electron pairs. It is the intent of this review to present the still limited number of synthetic approaches to C-Xe compounds and to organize their presently known reactivities into categories. It is hoped that C-Xe compounds can be introduced in the future as precursors in synthetic organic and organoelement chemistry.

Frohn H. , Bardin V.
Preparation and reactivity of compounds containing a carbon-xenon bond
Organometallics. 2001. V.20. N23. P.4750-4762. DOI: 10.1021/om010490j WOS Scopus РИНЦ

Published online:	Oct 12, 2001
Published print:	Nov 1, 2001

Web of science	WOS:000172243200002
Scopus	2-s2.0-0035851961
Elibrary	14097817
OpenAlex	W2087751101